121074-32-6

Basic information

• Product Name: (R)-4-[(R)-2-(Toluene-4-sulfonyloxymethyl)-butyl]-2,3,3a,4,5,7-hexahydro-1H-pyrrolo[2,3-d]carbazole-6-carboxylic acid methyl ester
• CAS NO: 121074-32-6
• Molecular Weight: 510.654
• Mol File: 121074-32-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-4-[(R)-2-(Toluene-4-sulfonyloxymethyl)-butyl]-2,3,3a,4,5,7-hexahydro-1H-pyrrolo[2,3-d]carbazole-6-carboxylic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-4-[(R)-2-(Toluene-4-sulfonyloxymethyl)-butyl]-2,3,3a,4,5,7-hexahydro-1H-pyrrolo[2,3-d]carbazole-6-carboxylic acid methyl ester(121074-32-6)
• EPA Substance Registry System: (R)-4-[(R)-2-(Toluene-4-sulfonyloxymethyl)-butyl]-2,3,3a,4,5,7-hexahydro-1H-pyrrolo[2,3-d]carbazole-6-carboxylic acid methyl ester(121074-32-6)

Safety Data

• Hazardous Substances Data: 121074-32-6(Hazardous Substances Data)

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 109704-79-2 N^b-benzyl-21-hydroxy-D-seco-Ψ-vincadifformine 
• 109704-80-5 N^b-benzyl-21-(tosyloxy)-D-seco-Ψ-vincadifformine 
• 109704-80-5 N^b-benzyl-21-(tosyloxy)-D-seco-Ψ-vincadifformine 

Downstream Products

• 73836-92-7 (+/-)-20-Epipseudovincadifformine 
• 26251-92-3 (+/-)-14-Epipseudovincadifformine 
• 57194-39-5 C₄₆H₅₈N₄O₈ 
• 3327-43-3 C₂₁H₂₈N₂O₂ 
• 3327-43-3 C₂₁H₂₈N₂O₂ 
• 28808-73-3 14'-epi-20'-deoxyvincovaline 
• 3327-43-3 C₂₁H₂₈N₂O₂ 
• 3327-43-3 C₂₁H₂₈N₂O₂ 

Relevant articles and documents

Syntheses of 20'-Deoxyvinblastine, 20'-Deoxyleurosidine, 20'-Deoxyvincovaline, 20'-epi-20'-Deoxyvincovaline, and 20'-Deoxyvincristine and Its 20'-Epimer through Racemic and Enantioselectively Generated Intermediates. New Syntheses of D/E-cis- and -trans-Ψ

Vindoline (20), on reaction with chloro imine derivatives of the D-seco-D/E-trans-Ψ- and -20-epi-Ψ-vincadifformines 18 and 19, followed by cyclization and debenzylation steps, provided the natural products 20'-deoxyvinblastine (4) and 20'-deoxyleurosidine