109748-85-8Relevant academic research and scientific papers
DER ERSTE METALLKOMPLEX DES UNSUBSTITUIERTEN SULFINS, CH2SO
Herberhold, Max,Hill, Anthony F.
, p. C29 - C33 (1986)
The electron-rich thioformaldehyde complex, OsCl(NO)(CH2S)(PPh3)2, is oxidized by 3-chloroperbenzoic acid at the sulphur atom to give the first example of a complex containing an unsubstituted sulfine, CH2SO.Spectroscopic data for OsCl(NO)(CH2SO)(PPh3)2 are compared with those of the isolobally related SO2 complex, OsCl(NO)(SO2)(PPh3)2, prepared from OsCl(NO)(PPh3)3 and SO2.
