DER ERSTE METALLKOMPLEX DES UNSUBSTITUIERTEN SULFINS, CH2SO

DOI: 10.1016/S0022-328X(00)99597-4

Source and publish data:

Journal of Organometallic Chemistry p. C29 - C33 (1986)

Update date:2022-07-29

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Authors:

Herberhold, Max

Hill, Anthony F.

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Article abstract of DOI:10.1016/S0022-328X(00)99597-4

The electron-rich thioformaldehyde complex, OsCl(NO)(CH2S)(PPh3)2, is oxidized by 3-chloroperbenzoic acid at the sulphur atom to give the first example of a complex containing an unsubstituted sulfine, CH2SO.Spectroscopic data for OsCl(NO)(CH2SO)(PPh3)2 are compared with those of the isolobally related SO2 complex, OsCl(NO)(SO2)(PPh3)2, prepared from OsCl(NO)(PPh3)3 and SO2.

Full text of DOI:10.1016/S0022-328X(00)99597-4

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