109787-95-3Relevant academic research and scientific papers
Synthesis of 5-Vinyl-2-isoxazolines by Palladium-Catalyzed Intramolecular O-Allylation of Ketoximes
Fernandes, Rodney A.,Gangani, Ashvin J.,Panja, Arpita
supporting information, p. 6227 - 6231 (2021/08/18)
An efficient method for the synthesis of 5-vinyl-2-isoxazolines by Pd-catalyzed intramolecular O-allylation of ketoximes has been developed. The reaction involves Pd(0)-catalyzed π-allyl formation via leaving group ionization or Pd(II)-catalyzed allylic C-H activation followed by intramolecular nucleophilic oxime oxygen attack. This methodology has been elaborated to various value-added products by epoxidation, Wacker oxidation, cross-metathesis, hydroboration-oxidation, dihydroxylation, and catalytic hydrogenation.
Continuous Pd-Catalyzed Carbonylative Cyclization Using Iron Pentacarbonyl as a CO Source
Lopatka, Pavol,Markovi?, Martin,Koó?, Peter,Ley, Steven V.,Gracza, Tibor
, p. 14394 - 14406 (2019/11/11)
This work discloses a continuous flow carbonylation reaction using iron pentacarbonyl as source of CO. The described transformation using this surrogate was designed for use in commonly accessible flow equipment. Optimized conditions were applied to a sca
A facile synthesis of α-fluoro ketones catalyzed by [Cp*IrCl2]2
Ahlsten, Nanna,Bartoszewicz, Agnieszka,Agrawal, Santosh,Martin-Matute, Belen
supporting information; experimental part, p. 2600 - 2608 (2011/10/02)
Allylic alcohols are isomerized into enolates (enols) by [Cp*IrCl2]2. The enolates react with Selectfluor present in the reaction media. This method produces α-fluoro ketones as single constitutional isomers in high yields. Georg Thieme Verlag Stuttgart. New York.
Stereochemical studies on the preparation and subsequent reductive cleavage of 1,2-dioxolanes. Application to the synthesis of (±)-yashabushitriol
Feldman,Simpson
, p. 6985 - 6988 (2007/10/02)
(E)-Selective oxygenation of 1,2-disubstituted alkenylcyclopropanes, and subsequent SmI2 mediated cleavage of the 1,2-dioxolane products with retention of stereochemistry, leads to a concise synthesis of the plant metabolite (±)-yashabushitriol.
Stereoselective Intramolecular Iodoetherification of 4-pentene-1,3-diols: Synthesis of cis-2-(Iodomethyl)-3-hydroxytetrahydrofurans
Tamaru, Yoshinao,Hojo, Makoto,Kawamura, Shin-ichi,Sawada, Shuji,Yoshida, Zen-ichi
, p. 4062 - 4072 (2007/10/02)
Intramolecular iodoetherification of 4-pentene-1,3-diol and its monosubstituted derivatives, irrespective of the substitution pattern, provides cis-2-(iodomethyl)-3-hydroxytetrahydrofurans in high yields.The cis selectivity generally exceeds 95percent .So
