109950-15-4Relevant academic research and scientific papers
FUNCTIONALLY SUBSITUTED SULFUR-CONTAINING COMPOUNDS. 9. REASTIONS OF 2-OXIRANES WITH ACETIC ANHYDRIDE AND ACETYL CHLORIDE
Kalugin, V. E.,Litvinov, V. P.
, p. 1391 - 1394 (2007/10/02)
Reaction of 2-oxiranes with acetic anhydride gives a mixture of 3-(organylthio)-1,2-diacetoxypropane and 2-(organylthio)-1,3-diacetoxypropane, and with acetyl chloride a mixture of 2-chloro-3-(organylthio)-1-acetoxypropane and 3-chloro-2-(organylthio)-1-acetoxypropane.In both cases, the ratio of the isomers depends on the nature of the organylthio group and on the nature of the electrophile.
SYNTHESES OF 2-MERCAPTO- AND 2-ALKYLTHIO-1,3-PROPANEDIOL DERIVATIVES
Aveta, Raffaele,Brandt, Alberto,Corsi, G. Bruno,Costanza, Angela Mitidieri
, p. 649 - 652 (2007/10/02)
Some synthetic routes to 2-alkylthio-1,3-propanediol derivatives, starting from commercially available compounds, are discussed.Treatment of diethyl 2-chloromalonate with thiolate anions followed by LiAlH4 reduction gave 9a,b,c in nearly 30percent overall
