111-54-6 Usage
Uses
Used in Pesticide Industry:
Ethylenebisdithiocarbamic acid is used as a pesticide for its ability to control various pests that damage crops and plants. It helps protect agricultural produce from pests, ensuring a higher yield and better quality of the harvested products.
Used in Fungicide Industry:
Ethylenebisdithiocarbamic acid is used as a fungicide to prevent and treat fungal infections in crops and plants. It helps maintain the health of the plants and reduces the risk of crop loss due to fungal diseases.
Air & Water Reactions
Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids.
Reactivity Profile
ETHYLENEBISDITHIOCARBAMIC ACID, SALTS & ESTERS are dithiocarbamic acid derivatives. Flammable gases are generated by the combination of thiocarbamates and dithiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates and dithiocarbamates are incompatible with acids, peroxides, and acid halides.
Health Hazard
Inhalation of material may be harmful. Contact may cause burns to skin and eyes. Inhalation of Asbestos dust may have a damaging effect on the lungs. Fire may produce irritating, corrosive and/or toxic gases. Some liquids produce vapors that may cause dizziness or suffocation. Runoff from fire control may cause pollution.
Fire Hazard
Some may burn but none ignite readily. Containers may explode when heated. Some may be transported hot.
Check Digit Verification of cas no
The CAS Registry Mumber 111-54-6 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,1 and 1 respectively; the second part has 2 digits, 5 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 111-54:
(5*1)+(4*1)+(3*1)+(2*5)+(1*4)=26
26 % 10 = 6
So 111-54-6 is a valid CAS Registry Number.
InChI:InChI=1/C4H8N2S4.2H3N/c7-3(8)5-1-2-6-4(9)10;;/h1-2H2,(H2,5,7,8)(H2,6,9,10);2*1H3
111-54-6Relevant academic research and scientific papers
SYNTHESIS OF 2,2'-(ALKYLENEDIAMINO)DIBENZAZOLES: NEW HETEROCYCLIC TETRADENTATE LIGANDS.
Melendez, E.,Merchan, F. L.,Tejero, T.,Merino, P.,Garcia, M.
, p. 487 - 490 (2007/10/02)
A new preparation of dimethyl N,N'-(alkylene)bisdithiocarbamates and tetramethyl N,N'-(alkylene)bisdithiocarbonimidates from aliphatic diamines is reported.The reaction of the dimethyl bis(dithiocarbamates) with several aromatic dinucleophiles provides a new entry to dibenzothiazoles, dibenzoxazoles and dibenzimidazoles.Since the two heterocyclic units are connected in all cases by a flexible bridge, the title compounds represent new and promising tetradentate ligands towards the formation of a variety of cationic or neutral complexes with metal atoms.Key words:Bisdithiocarbamates; Bisdithiocarbonimidates; Diheterocycles; Dibenzothiazoles; Dibenzoxazoles; Dibenzimidazoles
Synthesis and radioprotective effects of disodium alkanebisdithiocarbamates, ω aminoalkyldithiocarbamic acids and their N,N dimethyl derivatives
Barnes,Fatome,Esslemont,et al.
, p. 619 - 622 (2007/10/04)
The 12 compounds studied containing the dithiocarbamate group, 5 of which are new, showed remarkably low acute toxicity in mice, with LD50 values generally higher than 1,000 mg/kg by the intraperitoneal route. Most noteworthy was 2 aminoethyldithiocarbamic acid, which protected 100% of mice against an LD99 of whole body γ-radiation in dose of 750 mg/kg, while the LD50 exceeds 1,500 mg/kg: certain higher homologues and N-methylated derivatives were also radioprotective and the series may merit further study.
