111392-27-9

Upstream product

• 58706-24-4 (±)-3-O-benzyl-1,2:4,5-di-O-isopropylidene-myo-inositol 
• 824-94-2 p-methoxybenzyl chloride 
• 100-39-0 benzyl bromide 
• 111392-25-7 (+/-)-1,2:4,5-di-O-isopropylidene-3-O-p-methoxybenzyl-myo-inositol 
• 51548-88-0 (+/-)-1,2:4,5-di-O-isopropylidene-myo-inositol 

Downstream Products

• 58706-24-4 (+/-)-6-O-benzyl-1,2:4,5-di-O-isopropylidene-myo-inositol 
• 131147-10-9 4,7,7-Trimethyl-3-oxo-2-oxa-bicyclo[2.2.1]heptane-1-carboxylic acid (3aS,4S,5R,6S,7S,7aS)-5,6,7-tris-benzyloxy-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-4-yl ester 
• 131147-10-9 4,7,7-Trimethyl-3-oxo-2-oxa-bicyclo[2.2.1]heptane-1-carboxylic acid (3aR,4R,5S,6R,7R,7aR)-5,6,7-tris-benzyloxy-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-4-yl ester 
• 131233-67-5 1,4,5,6-tetra-O-benzyl-2,3-isopropylidene-sn-myo-inositol 
• 131233-64-2 3,4,5,6-tetra-O-benzyl-1,2-isopropylidene-sn-myo-inositol 
• 261722-84-3 1,3,4,5-Tetra-O-benzyl-D-myo-inositol 
• 131147-14-3 1D-1,3,5,6-tetra-O-benzyl-myo-inositol 
• 131233-74-4 2-O,3-O,4-O,5-O-tetrabenzyl-L-myo-inositol 
• 131233-72-2 1,6-di-O-allyl-3,4,5-tri-O-benzyl-L-myo-inositol 
• 131147-11-0 (3aR,4S,5S,6R,7S,7aS)-4-Allyloxy-5,6,7-tris-benzyloxy-2,2-dimethyl-hexahydro-benzo[1,3]dioxole 
• 131146-89-9 (+/-)-1,5,6-tri-O-benzyl-2,3-O-isopropylidene-myo-inositol 
• 131233-66-4 (3aR,4S,5S,6R,7S,7aS)-5,6,7-Tris-benzyloxy-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-4-ol 
• 131233-63-1 (3aS,4R,5R,6S,7R,7aR)-5,6,7-Tris-benzyloxy-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-4-ol 
• 131233-71-1 1D-4-O-allyl-1,5,6-tri-O-benzyl-myo-inositol 

Relevant academic research and scientific papers

The preparation of intermediates for the synthesis of 1D-myo-inositol 1,4,5-triphosphate, a second messenger for signal transduction in cells

Racemic 1,2,4-tri-O-benzyl-5,6-O-isopropylidene-myo-inositol was prepared by a new route involving crotyl (but-2-enyl) ethers and converted into (-)-ω-camphanates to give the pure crystalline 1L-diastereoisomer and the chirally impure, syrupy 1D-diastereo

The synthesis and resolution of (+/-)-1,5,6-tri-O-benzyl-myo-inositol

Racemic 1,5,6-O-benzyl-myo-inositol was prepared by five routes and converted into 1,5,6-tri-O-benzyl-2,3-O-isopropylidene-myo-inositol, the camphanates of which were readily separated by chromatography.The absolute configurations of the chiral derivative

The Allyl Group for Protection in Carbohydrate Chemistry. Part 18. Allyl and Benzyl Ethers of myo-Inositol. Intermediates for the Synthesis of myo-Inositol Triphosphates

Racemic 1,2:4,5-di-O-isopropylidene-myo-inositol was converted into racemic 1,2,4-tri-O-benzyl-myo-inositol, 1,2,4-tri-O-p-methoxybenzyl-myo-inositol and 2,4,5-tri-O-benzyl-myo-inositol using allyl groups for 'temporary' protection.The benzyl ethers are required as intermediates for the synthesis of the 'second messenger', inositol 1,4,5-triphosphate and its metabolite, inositol 1,3,4-triphosphate. 1,2,3,4-Tetra-O-benzyl-myo-inositol, and its two monoallyl and monoprop-1-enyl ethers, were also prepared as model compounds for phosphorylation studies of the vicinal 5,6-diol system which occurs in 1,2,4-tri-O-benzyl-myo-inositol.