111462-28-3

Upstream product

• 111462-27-2 (1S,2R)-1-(benzyloxy)-1-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)pent-4-en-2-ol 
• 104322-67-0 (R)-2-Benzyloxy-2-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-ethanol 
• 104322-68-1 (2S)-benzyloxy-[(4S)-2,2-dimethyl-[1,3]dioxolan-4-yl]-acetaldehyde 
• 111462-27-2 (1R,2S)-1-Benzyloxy-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-pent-4-en-2-ol 
• 100906-42-1 2-O-benzyl-3,4-O-isopropylidene-L-threose 
• 100-39-0 benzyl bromide 
• 38270-72-3 dimethyl 2,3-O-benzylidene-L-tartrate 

Downstream Products

• 111462-29-4 Benzoic acid (2S,3S,4S)-6-acetoxy-2-acetoxymethyl-3-benzyloxy-tetrahydro-pyran-4-yl ester 
• 111462-29-4 Benzoic acid (2S,3R,4S)-6-acetoxy-2-acetoxymethyl-3-benzyloxy-tetrahydro-pyran-4-yl ester 

Relevant academic research and scientific papers

STEREOSELECTIVE ALLYLATION FOR PREPARATION OF L-HEXOSE DERIVATIVES

The reaction of allyltrimethylsilane with α,β-dialkoxyaldehydes is catalyzed by magnesium bromide, and provides for a highly stereoselective allylation which is predicted by α-chelation of the Lewis acid.The observed stereocontrol is opposite to that gene