112052-21-8

Basic information

• Product Name: methyl 2-(cyclohex-2-en-1-yl)acetate
• Synonyms: methyl 2-(cyclohex-2-en-1-yl)acetate
• CAS NO: 112052-21-8
• Molecular Weight: 154.209
• Mol File: 112052-21-8.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: methyl 2-(cyclohex-2-en-1-yl)acetate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-(cyclohex-2-en-1-yl)acetate(112052-21-8)
• EPA Substance Registry System: methyl 2-(cyclohex-2-en-1-yl)acetate(112052-21-8)

Safety Data

• Hazardous Substances Data: 112052-21-8(Hazardous Substances Data)

Upstream product

• 36850-80-3 [(1-methoxyvinyl)oxy]trimethylsilane 
• 76644-52-5 rac-3-acetoxycyclohexene 
• 3675-31-8 2-(cyclohex-2-enyl)acetic acid 
• 77-78-1 dimethyl sulfate 
• 74-88-4 methyl iodide 
• 186581-53-3 diazomethane 
• 34939-28-1 dimethyl 2-(cyclohex-2-en-1-yl)malonate 
• 96-32-2 bromoacetic acid methyl ester 
• 822-67-3 Cyclohex-2-enol 
• 1521-51-3 rac-3-bromocyclohexene 
• 86769-61-1 ((1R,2S)-2-Phenylsulfanyl-cyclohexyl)-acetic acid methyl ester 
• 5401-62-7 1,2-dibromocyclohexane 
• 6305-63-1 diethyl 2-(cyclohex-2-enyl)malonate 
• 2138-99-0 cyclohex-2-enyl-malonic acid 

Downstream Products

• 55751-36-5 perfluoro(7-oxabicyclo<4.3.0>nonane) 
• 74317-65-0 perfluoro(cyclohexylacetyl fluoride) 
• 74179-30-9 perfluoro(8-methoxy-7-oxabicyclo<4.3.0>nonane) 
• 19656-95-2 2-cyclohexenylacetaldehyde 
• 82700-05-8 2-(cyclohex-2-en-1-yl)acetonitrile 
• 3675-31-8 2-(cyclohex-2-enyl)acetic acid 
• 16423-30-6 2-(Δ²-Cyclohexenyl)-ethyl-p-brom-benzolsulfonat 
• 221617-23-8 N-[2-(cyclohex-2-enyl)ethyl]-6-iodo-1,3-benzodioxole-5-methanamine 
• 221617-24-9 N-chloro-N-[2-(cyclohex-2-enyl)ethyl]-6-iodo-1,3-benzodioxole-5-methanamine 
• 16452-34-9 2-(cyclohex-2-enyl)ethanol 
• 69504-98-9 3-(2-Cyclohexenyl)-1-nitropropan 
• 172606-16-5 N-(2-(cyclohex-2-enyl)ethyl)toluene-4-sulfonamide 
• 172606-17-6 (2-Cyclohex-2-enyl-ethyl)-carbamic acid benzyl ester 
• 672903-58-1 2-(2-cyclohexenyl)ethyl methanesulfonate 

Relevant articles and documents

Radical cyclizations. A convergent total synthesis of (±)-γ-Lycorane

(±)-γ-Lycorane has been synthesized in 10 steps from piperonylic alcohol. Two radical reactions were used successively to build the D and B rings.

Allylic alkylation with function-bearing organozinc reagents

The first palladium-catalysed alkylations of allylic acetates with organozinc reagents bearing functionality are reported.The reaction proceeds well from ethanoate, and propanoates, derived organozinc halides and provides a useful method for transferring these moieties to an allyl fragment.The reaction proceeds through a monophosphine complex; attempts to perform asymmetric syntheses are unsuccessful so far. - Keywords: palladium; coupling; allylic substitution

Diastereoselectivity in the epoxidation of substituted cyclohexenes by dimethyldioxirane

Three series of compounds based on the cyclohexene framework have been epoxidized by dimetbyldioxirane. A pronounced dependence of epoxide diastereoselectivity on substituent has been observed. In addition there is a solvent influence on this stereoselectivity. The results have been explained by invoking steric, H-bonding, and dipole - dipole influences on the epoxide stereochemistry.