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Cyclohexylamidophosphoric acid diethyl ester is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

32405-88-2

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32405-88-2 Usage

Synthesis Reference(s)

Journal of the American Chemical Society, 96, p. 5937, 1974 DOI: 10.1021/ja00825a042

Check Digit Verification of cas no

The CAS Registry Mumber 32405-88-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,2,4,0 and 5 respectively; the second part has 2 digits, 8 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 32405-88:
(7*3)+(6*2)+(5*4)+(4*0)+(3*5)+(2*8)+(1*8)=92
92 % 10 = 2
So 32405-88-2 is a valid CAS Registry Number.
InChI:InChI=1/C10H22NO3P/c1-3-13-15(12,14-4-2)11-10-8-6-5-7-9-10/h10H,3-9H2,1-2H3,(H,11,12)

32405-88-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name N-diethoxyphosphorylcyclohexanamine

1.2 Other means of identification

Product number -
Other names diethylcyclohexylamidophosphate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:32405-88-2 SDS

32405-88-2Relevant academic research and scientific papers

Diselenide-Mediated Catalytic Functionalization of Hydrophosphoryl Compounds

Handoko,Benslimane, Zacharia,Arora, Paramjit S.

supporting information, p. 5811 - 5816 (2020/07/27)

We report a diaryldiselenide catalyst for cross-dehydrogenative nucleophilic functionalization of hydrophosphoryl compounds. The proposed organocatalytic cycle closely resembles the mechanism of the Atherton-Todd reaction, with the catalyst serving as a recyclable analogue of the halogenating agent employed in the named reaction. Phosphorus and selenium NMR studies reveal the existence of a P-Se bond intermediate, and structural analyses indicate a stereospecific reaction.

Tf2O-Promoted Activating Strategy of Phosphate Analogues: Synthesis of Mixed Phosphates and Phosphinate

Huang, Hai,Ash, Jeffrey,Kang, Jun Yong

supporting information, p. 4938 - 4941 (2018/08/24)

A metal-, toxic chloride reagent-free activating strategy of various phosphates has been developed. This method enables the facile synthesis of functional phosphates such as alkyl phosphates, aza phosphates, thiophosphate, and mixed diaryl phosphates. A transient phosphorylpyridin-1-ium species in situ generated from phosphates with Tf2O/pyridine readily undergoes a substitution reaction with diverse nucleophiles to form versatile phosphate compounds.

Fe3O4@MgO nanoparticles as an efficient recyclable catalyst for the synthesis of phosphoroamidates via the Atherton-Todd reaction Dedicated to Professor Tsutomu Yokomatsu from Tokyo University of Pharmacy and Life Sciences on the occasion of his 65th birthday

Kaboudin, Babak,Kazemi, Foad,Habibi, Fereshteh

supporting information, p. 6364 - 6367 (2015/11/16)

A simple and efficient method is presented for the synthesis of phosphoroamidates in moderate to good yield via the Atherton-Todd coupling of primary amines with H-dialkyl phosphites using Fe3O4@MgO nanoparticles as a recyclable catalyst.

Stereospecific aerobic oxidative dehydrocoupling of P(O)H bonds with amines catalyzed by copper

Zhou, Yongbo,Yang, Jia,Chen, Tieqiao,Yin, Shuang-Feng,Han, Daoqing,Han, Li-Biao

supporting information, p. 400 - 402 (2014/04/17)

Copper-catalyzed stereospecific oxidative dehydrocouplings of P(O)H bonds with amines under air took place effi-ciently at room temperature to afford the corresponding amidophosphorus compounds in high yields. Mechanistic studies showed that this dehydroc

New benzotriazole-based reagents for the phosphonylation of various N-, O-, and S-nucleophiles

Panmand, Deepak S.,Tiwari, Anand D.,Panda, Siva S.,Monbaliu, Jean-Christophe M.,Beagle, Lucas K.,Asiri, Abdullah M.,Stevens, Christian V.,Steel, Peter J.,Hall, C. Dennis,Katritzky, Alan R.

supporting information, p. 5898 - 5901 (2015/01/08)

Benzotriazole surrogates showing higher stabilities than the corresponding chlorophosphates, allow phosphonylation of a variety of N-, O-, and S-nucleophiles in good yields.

Phosphoramidate synthesis via copper-catalysed aerobic oxidative coupling of amines and H-phosphonates

Fraser, Jamie,Wilson, Laura J.,Blundell, Rebecca K.,Hayes, Christopher J.

supporting information, p. 8919 - 8921 (2013/09/24)

The copper-catalysed oxidative coupling of amines and H-phosphonates to produce phosphoramidates has been achieved using CuI as the catalyst and O 2 (present in air) as the sole oxidant.

Trichlorocyanuric acid: An efficient reagent for one-pot synthesis of Ptychodiscus brevis (PB-1) toxin and its derivatives

Gupta, Arvind K.,Acharya, Jyotiranjan,Dubey, Devendra K.,Kaushik, Mahabir P.

, p. 29 - 33 (2008/02/02)

Trichlorocyanuric acid is an efficient regent for simple and one-pot synthesis of dialkyl, N-cycloctylphosphoraamidates (PB-1) and its various derivatives in excellent yields. The procedure is operationally simple and involves the reaction of various dialkylphosphites with trichloroisocyanuric acid in acetonitrile and subsequent treatment with amines in presence KF-celite to give PB-1 and derivatives.

New route to O,O-diethyl phosphorocyanidate

Lopusinski, Andrzej

, p. 395 - 397 (2007/10/03)

A new and efficient route for synthesis of O, O-Diethyl Phosphorocyanidate by decomposition of diethyl phosphoryl-1,2,4,-dithiazolin-5-one was discussed. The use of phosphorocyanidates as coupling reagents in peptide chemistry and other applications of these compounds in organic synthesis was also demonstrated. It was found that these compounds were relatively unstable and could decompose easily, especially in the presence of water with the formation of hydrogen cyanide. A new efficient route to O, O-dialkyl phosphorocyamidates was offered, which were not contaminated by isomeric isocyanidates and could be used as the substrates for further synthetic purposes.

Carbodiimide compounds, polymers containing same and coating compositions containing said polymers

-

, (2008/06/13)

Carbodiimide compounds having the following structural formula are claimed: STR1 Z being selected from the group consisting of the following moieties: STR2 wherein R1 represents an alkylidene radical; R2 represents hydrogen or an alk

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