112212-81-4

Basic information

• Product Name: (+/-)-(1S,2R,3R,4S)-1,4-diacetoxy-2,3-dibromocyclohex-5-ene
• CAS NO: 112212-81-4
• Molecular Weight: 356.011
• Mol File: 112212-81-4.mol

Chemical Properties

• CAS DataBase Reference: (+/-)-(1S,2R,3R,4S)-1,4-diacetoxy-2,3-dibromocyclohex-5-ene(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-(1S,2R,3R,4S)-1,4-diacetoxy-2,3-dibromocyclohex-5-ene(112212-81-4)
• EPA Substance Registry System: (+/-)-(1S,2R,3R,4S)-1,4-diacetoxy-2,3-dibromocyclohex-5-ene(112212-81-4)

Safety Data

• Hazardous Substances Data: 112212-81-4(Hazardous Substances Data)

Upstream product

• 108-24-7 acetic anhydride 
• 69945-44-4 (1RS,2SR,3RS,4RS)-2,3-dibromocyclohex-5-ene-1,4-diol 
• 317821-92-4 2,3-dibromocyclohex-5-ene-1,4-diol 
• 106-51-4 p-benzoquinone 
• 5273-61-0 (5RS,6RS)-5,6-dibromocyclohex-2-ene-1,4-dione 

Downstream Products

• 145047-67-2 Acetic acid (1R,2S,3S,4R,5S,6R)-4-acetoxy-2,3-dibromo-5,6-dihydroxy-cyclohexyl ester 
• 169529-92-4 (+)-(1R,2S,3S,4R)-2,3-dibromocyclohex-5-ene-1,4-diol 
• 122-79-2 Phenyl acetate 
• 170210-89-6 (+)-(1S,2R,3R,4S)-1,4-diacetoxy-2,3-dibromocyclohex-5-ene 
• 39078-08-5 rac-(3R,4R,5R,6R)-3,4:5,6-diepoxycyclohex-1-ene 
• 18376-35-7 (1α,2β,3α,4β,5β,6β)-1,2-dibromo-3,4,5,6-tetraacetoxycyclo-hexane 
• 4381-96-8 (+/-)-tetraacetylconduritol C 
• 526-87-4 (+/-)-conduritol C 
• 61825-76-1 (+/-)-1-bromo-1-deoxyconduritol B 
• 61825-76-1 (+/-)-1-bromo-1-deoxyconduritol F 
• 526-87-4 (+/-)-Conduritol B 
• 222420-83-9 D-myo-3,6-bis-O-(di-O-benzylphospho)-4,5-bis-O-(2-oxo-5,6-benzo-1,3,2-dioxaphosphep-2-yl)inositol 

Relevant articles and documents

Synthesis of novel mono and bis-indole conduritol derivatives and their α/β-glycosidase inhibitory effects

Here we synthesized four novel indole conduritol derivatives 1-4 for the first time in the literature and probed their biological activities with the α and β-glucosidases. The compounds showed quite effective glucosidase inhibitory action. IC50

New Stereoselective Route to the Epoxyquinol Core of Manumycin-Type Natural Products. Synthesis of Enantiopure (+)-Bromoxone, (-)-LL-C10037α, and (+)-KT 8110

A practical route is decribed for the preparation of the C7N core of manumycin-type compounds. Starting from p-benzoquinone, optically pure compounds in both forms can be prepared via enzymatic resolution of a derived diacetoxy conduritol. A diepoxy aminoinositol is accessible which can function for formation of enantiopure epoxyquinones and quinols. Examples are given for acylation reactions of this amine with several acyl derivatives. With this approach (-)-LL-C10037α and quinones such as (+)-KT-8110 with 5A,6S-configuration can be synthesized through oxidation. In addition a short route to (+)-bromoxone is described. Most steps include simple epoxide formation and cleavage reactions which all can be carried out in a high stereoselective manner.

Enzyme-assisted total synthesis of the optical antipodes D-myo-inositol 3,4,5-trisphosphate and D-myo-inositol 1,5,6-trisphosphate: Aspects of their structure-activity relationship to biologically active inositol phosphates

Unambiguous total syntheses of both optical antipodes of the enantiomeric pair D-myo-inositol 3,4,5-trisphosphate (Ins(3,4,5)P3) and D- myo-inositol 1,5,6-trisphosphate (Ins(1,5,6)P3) are described. The ring system characteristic of

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