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Phenyl acetate
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2-phenylacetate
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No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
Phenyl acetate
Cas No: 122-79-2
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
TIANFU CHEM- PHENYL ACETATE
Cas No: 122-79-2
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Wholesale price CAS 122-79-2 with best price
Cas No: 122-79-2
USD $ 139.0-210.0 / Kilogram 1 Kilogram 1000 Kilogram/Day Zhuozhou Wenxi import and Export Co., Ltd Contact Supplier
122-79-2 Phenyl acetate
Cas No: 122-79-2
USD $ 40.0-50.0 / Gram 1 Gram 1000 Metric Ton/Day WUHAN MULEI NEW MATERIAL CO., LTD Contact Supplier
Phenyl Acetate 99% cas 122-79-2
Cas No: 122-79-2
No Data 25 Kilogram 100 Metric Ton/Month Hangzhou Sartort Biopharma Co., Ltd Contact Supplier
Phenyl Acetate 99% Ready stock cas 122-79-2
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No Data 1 Kilogram 1 Metric Ton/Day Hangzhou Fonlynn Health Technology Co., Ltd. Contact Supplier
Phenyl acetate
Cas No: 122-79-2
No Data No Data 10000 Metric Ton/Month Henan Wentao Chemical Product Co., Ltd. Contact Supplier

122-79-2 Usage

Air & Water Reactions

Slightly soluble in water.

Uses

Phenyl Acetate is a metabolite of Phenylbutyrate (PB), useful in the treatment of neuroblastoma and lung cancer. An odorant found in strawberries, passion fruit and black tea.

Health Hazard

Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Reactivity Profile

An ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

General Description

A clear colorless liquid with a sweetish solvent odor. Specific gravity 1.073. Flash point 176°F. Boiling point 383-384°F. Difficult to ignite. Used as a laboratory reagent and in the production of some organic chemicals.

Chemical Properties

colourless liquid

Chemical Properties

Phenylacetate, a product of phenylalanine metabolism. It is a small molecule normally present in the mammalian circulation in low concentrations. Phenylacetate has an offensive odor.

Purification Methods

Phenyl acetate acid is freed from phenol and acetic acid by washing (either directly or as a solution in pentane) with aqueous 5% Na2CO3, then with saturated aqueous CaCl2, drying with CaSO4 or Na2SO4, and fractionally distilling under reduced pressure. [Beilstein 6 II 153, 6 III 595, 6 IV 611.]

Definition

ChEBI: An acetate ester obtained by the formal condensation of phenol with acetic acid.

Safety Profile

Moderately toxic by ingestion. Mildly toxic by skin contact. A skin irritant. Combustible when exposed to heat, flame oroxidizers. To fight fire, use alcohol foam. When heated to decomposition it emits acrid smoke and irritating fumes.

Synthesis Reference(s)

Tetrahedron Letters, 29, p. 4567, 1988 DOI: 10.1016/S0040-4039(00)80548-1Chemical and Pharmaceutical Bulletin, 30, p. 4242, 1982 DOI: 10.1248/cpb.30.4242Synthetic Communications, 19, p. 1271, 1989 DOI: 10.1080/00397918908054534
InChI:InChI=1/C8H8O2/c1-7(9)10-8-5-3-2-4-6-8/h2-6H,1H3

122-79-2 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Alfa Aesar (B22561)  Phenyl acetate, 99%    122-79-2 250g 341.0CNY Detail
Alfa Aesar (B22561)  Phenyl acetate, 99%    122-79-2 1000g 1217.0CNY Detail

122-79-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name phenyl acetate

1.2 Other means of identification

Product number -
Other names PHENYL ACETATE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Food additives -> Flavoring Agents
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:122-79-2 SDS

122-79-2Synthetic route

acetic anhydride
108-24-7

acetic anhydride

phenol
108-95-2

phenol

Phenyl acetate
122-79-2

Phenyl acetate

Conditions
ConditionsYield
With pyridine; aluminum oxide at 103 - 105℃; for 2h; microwave irradiation;100%
With 2,6-di-tert-butyl-pyridine; sodium tetracarbonyl cobaltate In acetonitrile for 12h;100%
With SBA-15-Ph-Pr-SO3H at 20℃; for 0.25h;100%
Isopropenyl acetate
108-22-5

Isopropenyl acetate

phenol
108-95-2

phenol

A

acetone
67-64-1

acetone

B

Phenyl acetate
122-79-2

Phenyl acetate

Conditions
ConditionsYield
With potassium carbonate; Aliquat 336 In neat (no solvent) at 70℃; for 0.5h;A n/a
B 100%
With potassium carbonate; Aliquat 336 In neat (no solvent) at 70℃; for 0.5h; Product distribution;A n/a
B 100%
Ni(CH3)(OC6H5)(C10H8N2)
72918-80-0

Ni(CH3)(OC6H5)(C10H8N2)

A

Ni(CO)2(2,2'-bipyridine)
14917-14-7

Ni(CO)2(2,2'-bipyridine)

B

Phenyl acetate
122-79-2

Phenyl acetate

Conditions
ConditionsYield
With carbon monoxide In tetrahydrofuran (N2 or Ar), complex dissolved in THF, evacuated, excess CO introduced at room temp.C for 0.3 h; IR;A n/a
B 100%
With carbon monoxide In tetrahydrofuran (N2 or Ar), complex dissolved in THF, evacuated, equimolar amount CO introduced at -78°C for 10 h; IR;A n/a
B 31%
acetyl chloride
75-36-5

acetyl chloride

phenol
108-95-2

phenol

Phenyl acetate
122-79-2

Phenyl acetate

Conditions
ConditionsYield
With trifluorormethanesulfonic acid In acetonitrile at 20℃; for 1h;99%
In cyclohexane at 20℃; Solvent; Temperature;99%
montmorillonite K-10 In dichloromethane for 2h; Ambient temperature;98%
acetophenone
98-86-2

acetophenone

Phenyl acetate
122-79-2

Phenyl acetate

Conditions
ConditionsYield
With oxone; silica gel In dichloromethane at 20℃; for 16h; Baeyer-Villiger oxidation;99%
With 3-chloro-benzenecarboperoxoic acid In water at 80℃; for 2h; Oxidation;89%
With 3-chloro-benzenecarboperoxoic acid In water at 80℃; for 1.5h;85%
vinyl acetate
108-05-4

vinyl acetate

phenol
108-95-2

phenol

Phenyl acetate
122-79-2

Phenyl acetate

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane In neat (no solvent) at 70 - 140℃; for 0.183333h; Catalytic behavior; Temperature; Solvent; Reagent/catalyst; Time; Microwave irradiation;99%
With Rasta resin-(1,5,7-triazabicyclo[4.4.0]dec-5-ene)[RR-TBD] In tetrahydrofuran at 20 - 60℃;97%
With 4 A molecular sieve; tetrabutylammonium tricarbonylnitrosylferrate In hexane at 80℃; for 24h;80%
carbon monoxide
201230-82-2

carbon monoxide

methyl iodide
74-88-4

methyl iodide

phenol
108-95-2

phenol

Phenyl acetate
122-79-2

Phenyl acetate

Conditions
ConditionsYield
With iridium(III) chloride; triphenylphosphine In acetonitrile at 180℃; under 3750.38 Torr; for 20h; Autoclave;95%
1,1,1-Trifluoro-2-(acetyloxy)-2-propene
2247-91-8

1,1,1-Trifluoro-2-(acetyloxy)-2-propene

phenol
108-95-2

phenol

Phenyl acetate
122-79-2

Phenyl acetate

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane In neat (no solvent) at 60 - 140℃; for 0.183333h; Microwave irradiation;93%
4-acetoxyphenyl tosylate
82969-01-5

4-acetoxyphenyl tosylate

Phenyl acetate
122-79-2

Phenyl acetate

Conditions
ConditionsYield
With dimethylamine borane; potassium carbonate; tricyclohexylphosphine; bis(triphenylphosphine)nickel(II) chloride In N,N-dimethyl-formamide at 20℃; for 14h;92%
cycl-isopropylidene malonate
2033-24-1

cycl-isopropylidene malonate

phenol
108-95-2

phenol

Phenyl acetate
122-79-2

Phenyl acetate

Conditions
ConditionsYield
With triethylamine In toluene for 12h; Inert atmosphere; Reflux;92%
acetophenone
98-86-2

acetophenone

A

benzoic acid methyl ester
93-58-3

benzoic acid methyl ester

B

Phenyl acetate
122-79-2

Phenyl acetate

Conditions
ConditionsYield
With hydrogenchloride In chloroform at 20℃; for 11h; Baeyer-Villiger oxidation;A 7%
B 91%
With methyltrifluoromethyldioxirane; (η5-C5H4SiMe3)2NbH(O)C=CPh2 In tetrahydrofuran at 25℃;
With (η5-C5H4SiMe3)2NbH(O)C=CPh2 at 25℃;
With α,α,α-trifluorotoluene; 3-chloro-benzenecarboperoxoic acid In chloroform for 3.5h; Ambient temperature;
DMAE phenylacetate
866569-33-7

DMAE phenylacetate

diethyl ether
60-29-7

diethyl ether

methyl iodide
74-88-4

methyl iodide

Phenyl acetate
122-79-2

Phenyl acetate

Conditions
ConditionsYield
In acetone90%
Ni(CH3)(OC6H5)(P(C2H5)3)2
95910-33-1

Ni(CH3)(OC6H5)(P(C2H5)3)2

A

(CO)2Ni(P(C2H5)3)2
16787-33-0

(CO)2Ni(P(C2H5)3)2

B

Phenyl acetate
122-79-2

Phenyl acetate

Conditions
ConditionsYield
With carbon monoxide In diethyl ether (N2 or Ar), complex dissolved in Et2O, evacuated, excess CO introduced at room temp. for 24 h; IR;A n/a
B 90%
acetic acid
64-19-7

acetic acid

benzene
71-43-2

benzene

A

biphenyl
92-52-4

biphenyl

B

Phenyl acetate
122-79-2

Phenyl acetate

Conditions
ConditionsYield
With air; zirconium tetraacetate; cobalt(II) acetate; palladium dichloride In acetylacetone at 105℃; under 7500.6 Torr; for 6h; Product distribution; Activation energy; Further Variations:; Catalysts; Reagents; Pressures; Temperatures; solvents, ratio;A 89%
B n/a
With air; zirconium tetraacetate; cobalt(II) acetate; palladium dichloride In acetylacetone at 105℃; under 7500.6 Torr; for 6h; Product distribution; Activation energy; Kinetics; Further Variations:; Catalysts; Reagents; Pressures; Temperatures; solvents, ratio;A 89%
B n/a
2-phenoxytetrahydropyran
4203-50-3

2-phenoxytetrahydropyran

acetic anhydride
108-24-7

acetic anhydride

Phenyl acetate
122-79-2

Phenyl acetate

Conditions
ConditionsYield
copper(II) sulfate In dichloromethane for 2.5h; Heating;89%
With 1,4-diaza-bicyclo[2.2.2]octane; bismuth (III) nitrate pentahydrate for 0.05h; Microwave irradiation;85%
With iron(III) sulfate In 1,2-dichloro-ethane for 1.5h; Heating;80%
acetic acid
64-19-7

acetic acid

methoxybenzene
100-66-3

methoxybenzene

Phenyl acetate
122-79-2

Phenyl acetate

Conditions
ConditionsYield
Stage #1: methoxybenzene With boron tribromide In dichloromethane at 0 - 20℃; Inert atmosphere;
Stage #2: acetic acid In dichloromethane at 0 - 20℃; Inert atmosphere;
88%
acetic acid
64-19-7

acetic acid

benzyl alcohol
100-51-6

benzyl alcohol

phenol
108-95-2

phenol

A

Benzyl acetate
140-11-4

Benzyl acetate

B

Phenyl acetate
122-79-2

Phenyl acetate

Conditions
ConditionsYield
With poly(4-vinylpyridine) perchlorate In neat (no solvent) at 20℃; for 0.5h;A 88%
B 12%
trimethylphenylsilane
768-32-1

trimethylphenylsilane

acetic acid
64-19-7

acetic acid

Phenyl acetate
122-79-2

Phenyl acetate

Conditions
ConditionsYield
With palladium diacetate; bis-[(trifluoroacetoxy)iodo]benzene at 80℃; for 17h;88%
N-acetyl saccharin
13361-42-7

N-acetyl saccharin

phenol
108-95-2

phenol

Phenyl acetate
122-79-2

Phenyl acetate

Conditions
ConditionsYield
In neat (no solvent) at 150℃; for 1h;87%
In neat (no solvent) at 150℃; Microwave irradiation;82%
Stage #1: phenol With aluminum (III) chloride In tetrahydrofuran at 20℃; for 1h;
Stage #2: N-acetyl saccharin In tetrahydrofuran for 1h; Reflux;
11%
1-Acetyl-4(1H)-pyridinon
30074-98-7

1-Acetyl-4(1H)-pyridinon

phenol
108-95-2

phenol

Phenyl acetate
122-79-2

Phenyl acetate

Conditions
ConditionsYield
In dichloromethane at 20℃; for 12h;86%
phenyltrimethylsilyl ether
1529-17-5

phenyltrimethylsilyl ether

acetic anhydride
108-24-7

acetic anhydride

Phenyl acetate
122-79-2

Phenyl acetate

Conditions
ConditionsYield
Sulfate; titanium(IV) oxide at 20℃; for 0.5h;85%
With polyvinylpolypyrrolidone-bound boron trifluoride In acetonitrile at 20℃; for 3h;85%
With silver perchlorate; titanium tetrachloride In dichloromethane Ambient temperature;62%
Phenyl acetate
122-79-2

Phenyl acetate

ethanol
64-17-5

ethanol

Conditions
ConditionsYield
With sodium aluminum tetrahydride In tetrahydrofuran at 0℃; for 0.0833333h;100%
With C17H16BrMnNO3P; potassium tert-butylate; hydrogen In 1,4-dioxane at 100℃; under 37503.8 Torr; for 16h; Autoclave;89%
Phenyl acetate
122-79-2

Phenyl acetate

phenol
108-95-2

phenol

Conditions
ConditionsYield
With HZSM-5(30) In water for 7h; Product distribution; Heating; var. catalysts; other acetylated alcohols;100%
silica gel; toluene-4-sulfonic acid In water; toluene at 80℃; for 6h;100%
With sodium hydrogen telluride; acetic acid In ethanol for 0.5h; Heating;100%
methanol
67-56-1

methanol

Phenyl acetate
122-79-2

Phenyl acetate

acetic acid methyl ester
79-20-9

acetic acid methyl ester

Conditions
ConditionsYield
With dilithium tetra(tert-butyl)zincate at 0℃; for 1h; Inert atmosphere;100%
With 2Zn(2+)*C20H14N4*4C2H3O2(1-)*1.5CH4O In neat (no solvent) at 50℃; for 18h;99%
With [Zn(bis(2-pyridylmethyl)amine)2]I2 at 50℃; for 48h;100 %Chromat.
4-nitrobenzyl chloride
619-73-8

4-nitrobenzyl chloride

Phenyl acetate
122-79-2

Phenyl acetate

4-nitrobenzyl acetate
619-90-9

4-nitrobenzyl acetate

Conditions
ConditionsYield
With C12F18O13Zn4 at 90℃; for 18h; Inert atmosphere;99%
Phenyl acetate
122-79-2

Phenyl acetate

4-aminoethylbenzene
589-16-2

4-aminoethylbenzene

N-(4-ethylphenyl)acetamide
3663-34-1

N-(4-ethylphenyl)acetamide

Conditions
ConditionsYield
With cell-free extract containing recombinant PpATaseCH In aq. phosphate buffer; dimethyl sulfoxide at 35℃; for 24h; pH=7.5; Time;99%
Phenyl acetate
122-79-2

Phenyl acetate

formic acid ethyl ester
109-94-4

formic acid ethyl ester

3-Ethoxyacrylsaeurephenylester
105786-68-3

3-Ethoxyacrylsaeurephenylester

Conditions
ConditionsYield
With titanium tetrachloride; triethylamine In dichloromethane at -20℃; for 1h; Inert atmosphere;98%
C40H61ClLiN3O2U

C40H61ClLiN3O2U

Phenyl acetate
122-79-2

Phenyl acetate

[(1,2,3,4,5-pentamethylcyclopentadiene)U(OPh)(HN3Mes)]

[(1,2,3,4,5-pentamethylcyclopentadiene)U(OPh)(HN3Mes)]

Conditions
ConditionsYield
In toluene for 1h;98%
m-ethylaniline
587-02-0

m-ethylaniline

Phenyl acetate
122-79-2

Phenyl acetate

3-acetylamino-1-ethylbenzene
51279-01-7

3-acetylamino-1-ethylbenzene

Conditions
ConditionsYield
With cell-free extract containing recombinant PpATaseCH In aq. phosphate buffer; dimethyl sulfoxide at 35℃; for 24h; pH=7.5; Time;98%
5-decyne
1942-46-7

5-decyne

Phenyl acetate
122-79-2

Phenyl acetate

3,4-dibutyl-2H-chromen-2-one

3,4-dibutyl-2H-chromen-2-one

Conditions
ConditionsYield
With copper acetylacetonate; tris(triphenylphosphine)ruthenium(II) chloride; di-n-butyliodotin hydride; 3-ethyl-1-methyl-1H-imidazol-3-ium 2,2,2-trifluoroacetate In 1,4-dioxane; dimethyl sulfoxide at 20 - 75℃; for 6h; Reagent/catalyst; Inert atmosphere;97.4%
1,2-bis(4-fluorophenyl)acetylene
5216-31-9

1,2-bis(4-fluorophenyl)acetylene

Phenyl acetate
122-79-2

Phenyl acetate

3,4-bis(4-fluorophenyl)-2H-chromen-2-one

3,4-bis(4-fluorophenyl)-2H-chromen-2-one

Conditions
ConditionsYield
With copper acetylacetonate; tris(triphenylphosphine)ruthenium(II) chloride; di-n-butyliodotin hydride; 3-ethyl-1-methyl-1H-imidazol-3-ium 2,2,2-trifluoroacetate In 1,4-dioxane; dimethyl sulfoxide at 20 - 80℃; for 6h; Reagent/catalyst; Inert atmosphere;97.3%
4,4'-dimethoxydiphenylacetylene
2132-62-9

4,4'-dimethoxydiphenylacetylene

Phenyl acetate
122-79-2

Phenyl acetate

3,4-bis(4-methoxyphenyl)-2H-chromen-2-one

3,4-bis(4-methoxyphenyl)-2H-chromen-2-one

Conditions
ConditionsYield
With copper acetylacetonate; tris(triphenylphosphine)ruthenium(II) chloride; di-n-butyliodotin hydride; 3-ethyl-1-methyl-1H-imidazol-3-ium 2,2,2-trifluoroacetate In 1,4-dioxane; dimethyl sulfoxide at 20 - 90℃; for 5h; Reagent/catalyst; Inert atmosphere;97.2%
aniline
62-53-3

aniline

Phenyl acetate
122-79-2

Phenyl acetate

Acetanilid
103-84-4

Acetanilid

Conditions
ConditionsYield
In tetrahydrofuran-d8 at 66℃; for 48h; Catalytic behavior; Temperature; Concentration;96%
With allylchloro-[1,3-bis(diisopropylphenyl)-imidazole-2-ylidene]palladium(II); water; potassium carbonate In toluene at 110℃; for 16h; Inert atmosphere;92%
With cell-free extract containing recombinant PpATaseCH In aq. phosphate buffer; dimethyl sulfoxide at 35℃; for 24h; pH=7.5; Time;70%
Phenyl acetate
122-79-2

Phenyl acetate

A

phenyl dithioacetate
36797-15-6

phenyl dithioacetate

B

O-phenyl ethanethioate
85033-96-1

O-phenyl ethanethioate

Conditions
ConditionsYield
With Lawessons reagent In xylene for 10h; Heating;A n/a
B 96%
m-Hydroxyaniline
591-27-5

m-Hydroxyaniline

Phenyl acetate
122-79-2

Phenyl acetate

meta-hydroxyacetanilide
621-42-1

meta-hydroxyacetanilide

Conditions
ConditionsYield
With cell-free extract containing recombinant PpATaseCH In aq. phosphate buffer; dimethyl sulfoxide at 35℃; for 24h; pH=7.5; Concentration;96%
Phenyl acetate
122-79-2

Phenyl acetate

4-bromophenyl acetate
1927-95-3

4-bromophenyl acetate

Conditions
ConditionsYield
With bromine fluoride In ethanol; chloroform at -78℃; for 0.25h;95%
With tetrachloromethane; N-Bromosuccinimide
With phosphorus pentabromide
With bromine fluoride; ethanol 1.) CFCl3, -75 deg C; 2.) CHCl3, -75 deg C, 5-15 min; Yield given. Multistep reaction;
Phenyl acetate
122-79-2

Phenyl acetate

o-hydroxyacetophenone
118-93-4

o-hydroxyacetophenone

Conditions
ConditionsYield
for 0.116667h; Rearrangement; microwave irradiation;95%
With aluminum (III) chloride In neat (no solvent) at 140 - 150℃; Fries Phenol Ester Rearrangement;90%
With hydrogen fluoride supported on silica gel In neat (no solvent) at 55℃; for 4h; Temperature; Green chemistry;77%

122-79-2Related news

A metal-free protocol for direct oxidative de-alkoxycarbonylation of alkyl PHENYL ACETATE (cas 122-79-2) by molecular iodine09/08/2019

A metal-free protocol for the direct oxidative de-alkoxycarbonylation of alkyl phenyl acetate has been carried out by molecular iodine with good yield. In the present Letter, the vital role of iodine in oxidative de-alkoxycarbonylation is described. This method has been proven to be tolerant to ...detailed

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