112424-11-0

Basic information

• Product Name: DL-(1α,2α,3α,4α,5β,6β)-6-O-(Methylsulfonyl)-1,2:3,4-bis-S-(1,2-phenylen)-1,2,3,4-tetrathio-1,2,3,4,5,6-cyclohexanhexol-5-<3,5-bis(trifluormethyl)benzolsulfonat>
• Synonyms: DL-(1α,2α,3α,4α,5β,6β)-6-O-(Methylsulfonyl)-1,2:3,4-bis-S-(1,2-phenylen)-1,2,3,4-tetrathio-1,2,3,4,5,6-cyclohexanhexol-5-<3,5-bis(trifluormethyl)benzolsulfonat>
• CAS NO: 112424-11-0
• Molecular Weight: 746.839
• Mol File: 112424-11-0.mol

Chemical Properties

• CAS DataBase Reference: DL-(1α,2α,3α,4α,5β,6β)-6-O-(Methylsulfonyl)-1,2:3,4-bis-S-(1,2-phenylen)-1,2,3,4-tetrathio-1,2,3,4,5,6-cyclohexanhexol-5-<3,5-bis(trifluormethyl)benzolsulfonat>(CAS DataBase Reference)
• NIST Chemistry Reference: DL-(1α,2α,3α,4α,5β,6β)-6-O-(Methylsulfonyl)-1,2:3,4-bis-S-(1,2-phenylen)-1,2,3,4-tetrathio-1,2,3,4,5,6-cyclohexanhexol-5-<3,5-bis(trifluormethyl)benzolsulfonat>(112424-11-0)
• EPA Substance Registry System: DL-(1α,2α,3α,4α,5β,6β)-6-O-(Methylsulfonyl)-1,2:3,4-bis-S-(1,2-phenylen)-1,2,3,4-tetrathio-1,2,3,4,5,6-cyclohexanhexol-5-<3,5-bis(trifluormethyl)benzolsulfonat>(112424-11-0)

Safety Data

• Hazardous Substances Data: 112424-11-0(Hazardous Substances Data)

Upstream product

• 112424-06-3 (1α,2β,3β,4α,5α,6α)-5,6-Epoxy-2,3-S-(1,2-phenylen)-2,3-dithio-1,2,3,4-cyclohexantetrol-1,4-bis<3,5-bis(trifluormethyl)benzolsulfonat> 
• 39234-86-1 3,5-bis(trifluoromethyl)benzenesulfonyl chloride 
• 39078-11-0 cis-trisoxirane 
• 112424-09-6 DL-(1α,2α,3α,4α,5β,6β)-1,2:3,4-Bis-S-(1,2-phenylen)-1,2,3,4-tetrathio-1,2,3,4,5,6-cyclohexanhexol-5-<3,5-bis(trifluormethyl)benzolsulfonat> 
• 7143-01-3 Methanesulfonic anhydride 
• 112424-03-0 (1α,2β,3β,4α,5α,6α)-5,6-Epoxy-2,3-S-(1,2-phenylen)-2,3-dithio-1,2,3,4-cyclohexantetrol 
• 17534-15-5 Benzene-1,2-dithiol 

Relevant articles and documents

cis-/trans--Trithia- and trans--Hexathia-tris-?-homobenzenes

Starting from the cis- and trans-benzene trioxides 2/7 the cis-/trans--Trithia-tris-?-homobenzenes 1/6 and the trans-dioxathia-/oxadithia analogs 19/21 are synthesized by regioselective epoxide opening reactions with appropriate S-nucleophiles.Under the influence of heat and light cis-trisulfide 1 quickly looses sulfur and does not undergo ?2+?2+?2>cycloreversion.Attempts to build up cis--tris-?-homobenzenes from 2 by threefold six-membered ring anellation, in the special case of 1,2-benzenedithiol as 1,4-dinucleophil, led preferably to the trans--hexathia-tris-?-homobenzene 44 (X-ray analysis) manifesting effective S-neighbouring group participation. cis-Trisulfide 1 is a poor tridentate ligand: only with Ni(ClO4)2 a 2:1 complex (presumably octahedral, 48) is formed.