112452-64-9

Upstream product

• 143-33-9 sodium cyanide 
• 110455-57-7 tert-Butyl-{(R)-2-[(4S,5S,6S)-6-((E)-(S)-1,4-dimethyl-pent-2-enyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-propoxy}-diphenyl-silane 
• 112452-63-8 Acetic acid (E)-(1S,2S,3S,4S)-3-acetoxy-1-[(S)-2-(tert-butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-2,4,7-trimethyl-oct-5-enyl ester 
• 81470-86-2 (R)-2-{(4R,5R,6S)-6-[(S)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-2,2,5-trimethyl-[1,3]dioxan-4-yl}-propionaldehyde 
• 81470-85-1 (S)-2-{(4S,5S,6S)-6-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-2,2,5-trimethyl-[1,3]dioxan-4-yl}-propan-1-ol 
• 110455-56-6 3(S)-(1(S),4-dimethyl-2(E)-pentenyl)-4(S)-methyl-5(R)-<1(S)-methyl-2<(tert-butyldiphenylsilyl)oxy>ethyl>dihydro-2(3H)-furanone 
• 115047-25-1 (E)-(2S,3S,4S,5S,6S)-1-(tert-Butyl-diphenyl-silanyloxy)-2,4,6,9-tetramethyl-dec-7-ene-3,5-diol 
• 103576-61-0 4(S)-methyl-5(R)-<1(S)-methyl-2-<(tert-butyldiphenylsilyl)oxy>ethyl>-dihydro-2(3H)furanone 
• 115047-24-0 (4S,5R)-5-[(S)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-3-((E)-(S)-1,4-dimethyl-pent-2-enyl)-4-methyl-2-oxo-tetrahydro-furan-3-carboxylic acid methyl ester 
• 112529-80-3 6(S)-(1(S),4-dimethyl-2(E)-pentenyl)-4(S)-<1(S)-methyl-2-<(tert-butyldiphenylsilyl)oxy>ethyl>-2,2,5(S)-trimethyl-1,3-dioxane 
• 115115-17-8 6(S)-(1(S)-methyl-2-hydroxyethyl)-4(S)-<1(S)-methyl-2-<(tert-butyldiphenylsilyl)oxy>ethyl>-2,2,5(S)-trimethyl-1,3-dioxane 
• 110410-93-0 3-carbomethoxy-4(S)-methyl-5(R)-<1(S)-methyl-2-<(tert-butyldiphenylsilyl)oxy>ethyl>dihydro-2(3H)-furanone 

Downstream Products

• 115047-26-2 (S)-3-{(4S,5S,6S)-6-[(S)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-2,2,5-trimethyl-[1,3]dioxan-4-yl}-butyric acid 

Relevant academic research and scientific papers

3-METHYL-γ-BUTYROLACTONE AS A SOURCE OF 2-METHYL-3-HYDROXYKETONES AND 2-METHYL-1,3-DIOLS: A SYNTHESIS OF THE C19-C27 FRAGMENT OF RIFAMYCIN S BY LINEAR ITERATION

3-Methyl-γ-butyrolactone has been employed as a source of 2-methyl-3-hydroxyketones after functioning as a template for the preparation of enantiomerically pure propionate chains.This method is exemplified by the preparation of the C19-C27 propionate frag