112473-05-9Relevant academic research and scientific papers
The Importance of Polar, Resonance, Steric and Solvent Effects in the Addition of Sulfonyl Radicals to Alkenes
Correa, Carlos M. M. da Silva,Fleming, M. Daniela C. M.,Oliveira, M. Augusta B. C. S.,Garrido, Ermelinda M. J.
, p. 1993 - 2000 (2007/10/02)
The radical chain addition of tosyl iodide to some alkenes has been studied.The reaction was carried out at room temperature under visible light, giving the usual high yields of β-iodo sulfones.These adducts were transformed into the corresponding unsatur
Reactions of (E)-2-Iodo-1-tosyl-1-alkenes as Useful Synthetic Intermediates
Iwata, Noriyoshi,Morioka, Tetsuro,Kobayashi, Toshifumi,Asada, Takahiro,Kinoshita, Hideki,Inomata, Katsuhiko
, p. 1379 - 1388 (2007/10/02)
(E)-2-Iodo-1-tosyl-1-alkenes readily available by iodosulfonization of 1-alkynes were found to be useful synthons for the regio- and/or stereoselective preparation of 1-tosyl-1-alkynes, 1-tosyl-2-alkynes, (Z)-vinyl and (Z)-allyl sulfones, β-tosyl enamines
Regio- and Stereoselective Synthesis of (E)- and (Z)-Vinylic Sulfones and Their Conversion to the Corresponding Allylic Sulfones
Kobayashi, Toshifumi,Tanaka, Yuhji,Ohtani, Takashi,Kinoshita, Hideki,Inomata, Katsuhiko,Kotake, Hiroshi
, p. 1209 - 1212 (2007/10/02)
(E)- and (Z)-vinilyc sulfones were prepared regio- and stereoselectively from 1-alkenes or 1-alkynes in high yields via iodosulfonization in AcOEt-H2O.The vinylic sulfones thus prepared were converted to the corresponding allylic sulfones by treatment wit
