90633-61-7

Upstream product

• 3913-80-2 (E)-2-octen-1-yl acetate 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 112473-05-9 (Z)-1-tosyl-1-octene 
• 111895-50-2 (E)-1-methyl-4-(oct-1-en-1-ylsulfonyl)benzene 
• 119365-13-8 (Z)-2-octenyl p-toluenesulfinate 
• 106708-08-1 (E)-2-octenyl p-toluenesulfinate 
• 629-05-0 n-octyne 
• 111-66-0 oct-1-ene 
• 28995-78-0 (E)-1-((2-iodooct-1-en-1-yl)sulfonyl)-4-methylbenzene 
• 158588-49-9 1-((2-iodooctyl)sulfonyl)-4-methylbenzene 

Relevant academic research and scientific papers

Regio- and Stereoselective Synthesis of (E)- and (Z)-Vinylic Sulfones and Their Conversion to the Corresponding Allylic Sulfones

(E)- and (Z)-vinilyc sulfones were prepared regio- and stereoselectively from 1-alkenes or 1-alkynes in high yields via iodosulfonization in AcOEt-H2O.The vinylic sulfones thus prepared were converted to the corresponding allylic sulfones by treatment wit

ASYMMETRIC INDUCTION IN THE PALLADIUM-CATALYZED SULFONYLATION OF ALLYLIC SULFINATES AND ACETATES WITH CHIRAL PHOSPHINE LIGANDS

Treatment of allylic (+/-)-p-toluenesulfinates with tetrakis-(triphenylphosphine) palladium in the presence of chiral phosphine ligands underwent allylic sulfinate-sulfone rearrangements to give the corresponding optically active allylic sulfones in high

Palladium-catalysed Allylic Sulphinate-Sulphone Rearrangements; Asymmetric Induction in the Palladium-catalysed Transfer of Chiral Sulphinates to Sulphones

The rearrangement of allylic sulphinates to sulphones is facilitated by palladium catalysis, treatment of the chiral trans- and cis-allyl sulphinates (S)-(-)-(1a), -(1c), and -(1e), and (S)-(-)-(1b) and -(1d) with a catalytic amount of the palladium catal