112612-41-6Relevant academic research and scientific papers
Definitive Synthesis of Methyl α-kedarosaminide, a Sugar Component of the Antitumor Antibiotic Kedarcidin
Hornyak, Miklos,Pelyvas, Istvan F.,Sztaricskai, Ferenc J.
, p. 4087 - 4090 (2007/10/02)
The first definitive synthesis and physical data of the α-methyl glycoside (methyl α-kedarosaminide (2) of kedarosamine (1), the aminodeoxy sugar component of the antibiotic kedarcidin is presented.
A Highly Stereoselective Synthesis of the AB Disaccharide Unit of Olivomycin A
Roush, William R.,Lin, Xiaofa,Straub, Julie A.
, p. 1649 - 1655 (2007/10/02)
A highly stereoselective synthesis of the AB disaccharide (4c) of olivomycin A is described.The synthesis features the double asymmetric allylboration of α,β-dialkoxy aldehyde 8 using tartrate allylboronate (S,S)-9, which provides triol derivative 10 with
