Chemistry of Natural Compounds p. 196 - 200 (1987)
Update date:2022-08-16
Topics:
Popova, L. A.
Kozlov, N. G.
Previously unknown secondary amines have been synthesized by the Ritter reaction of p-menthan-8-ol with propio- and benzonitriles.The performance of this reaction with α-terpeneol and benzonitrile led to the formation of a mixxture of N-(p-menth-1-en-8-y1)benzamide and N, N-(p-menth-1,8,diyl)dibenzamide.A transdiamide was also obtained on the reaction of α-terpineol with isovaleronitrile.The use of propionitrile as the nucleophile with α-terpineol led to the formation of 2-ethyl-4,4,8-trimethyl-8-propionamido-3-azabicyclo <3.3.1>non-2-ene.
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Doi:10.1007/BF00699141
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(1979)
