1129294-89-8Relevant articles and documents
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Reichstein et al.
, p. 510,519 (1934)
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Outer-Sphere Electron-Transfer Reactions of Ascorbate Anions
Williams, Nicola H.,Yandell, John K.
, p. 1133 - 1144 (2007/10/02)
Rate constants for the one-electron oxidation of ascorbate dianion (A2-) by bis(terpyridine)cobalt(III) ion (8.5*106 dm3 mol-1 s-1) and pentaammine(pyridine)ruthenium(III) ion (6.0*109 dm3 mol-1 s-1), and of the monoanion (HA-) by tetraammine(bipyridine)ruthenium(III) ion (2.1*105 dm3 mol-1 s-1) have been determined in aqueous solution at 25 deg C and ionic strength 0.1 (NaNO3 or NaClO4).It is shown that these rate constants, and other published rate constants for oxidation of HA- and A2-, are consistent with the Marcus cross relation, on the assumption that the self-exchange rate constants for both the HA-/HA. and A2-/A-. couples are 106 dm3 mol-1 s-1.One-electron redox potentials for the ascorbate/dehydroascorbate system have been derived from scattered literature data.