1133-62-6Relevant academic research and scientific papers
Synthesis of cyclohexylphenols
Postnova,Koshel',Lebedeva,Kuznetsova,Koshel'
, p. 1415 - 1417 (2007/10/03)
Catalytic alkylation of phenols with cyclohexanol gives o- and p-cyclohexylphenols as the major products. The effect of temperature, catalyst nature, and reactant concentration on the reaction outcome was studied.
Medium-scale preparation of useful metabolites of aromatic compounds via whole-cell fermentation with recombinant organisms
Endoma, Mary Ann,Bui, Vu P.,Hansen, Jeff,Hudlicky, Tomas
, p. 525 - 532 (2013/09/06)
The whole-cell fermentation of aromatic coumpounds with Escherichia coli JM109 (pDTG601) on a medium scale (10-15L) produces enantiopure cyclohexadienediols. A detailed procedure for the fermentation is described, and yields for several metabolites are provided. A similar procedure using E. coli JM109 (pDTG602) affords catechols. The dienediols are useful for asymmetric synthesis, and several important targets originating from these metabolites are tabulated.
ALKYLATION OF PYROCATECHOL AND RESORCINOL WITH CYCLOHEXENE IN THE PRESENCE OF ALUMINUM PHENOLATE
Kozlikovskii, Ya. B.,Koshchii, V. A.,Butov, S. A.,Ovsiyuk, T. F.
, p. 746 - 749 (2007/10/02)
The alkylation of pyrocatechol and resorcinol with cyclohexene in the presence of aluminum phenolate leads to a mixture of isomeric mono- and dicyclohexyldihydroxybenzenes, in which as a rule the ortho-alkylation products predominate.
