113386-95-1Relevant academic research and scientific papers
Cathodic intra- and intermolecular couplings of ketones with unsaturated silanes
Kashimura, Shigenori,Ishifune, Manabu,Murai, Yoshihiro,Moriyoshi, Naotake,Shono, Tatsuya
, p. 5041 - 5044 (1995)
The electroreduction of 6-trimethylsilyl-6-hepten-2-one afforded cis-1- methyl-3-trimethylsilyl cyclohexanol, and γ-trimethylsilyl alcohols were yielded as the intermolecular coupling products when the cathodic reduction of ketones was carried out in the presence of unsaturated silanes.
Investigation of 1,4-elimination reactions of γ-trimethylsilyl alcohols via ionic and radical processes
Hwu, Jih Ru,Gilbert, Bryant A.
, p. 53 - 62 (2007/10/02)
Oxidative fragmentation of γ-trimethylsilyl alcohols with cerium ammonium nitrate occurs rapidly via a radical processes to provide keto olefins.Attempts to obtain the same products via an ionic type 1,4-elimination with the trimethylsilyl group as the directing moiety proved unsuccesful, even under a variety of harsh experimental conditions.Instead, dehydration products were produced in certain cases.
