Cathodic intra- and intermolecular couplings of ketones with unsaturated silanes

DOI: 10.1016/00404-0399(50)09172-

Source and publish data:

Tetrahedron Letters p. 5041 - 5044 (1995)

Update date:2022-08-03

Topics:

Authors:

Kashimura, Shigenori

Ishifune, Manabu

Murai, Yoshihiro

Moriyoshi, Naotake

Shono, Tatsuya

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Article abstract of DOI:10.1016/00404-0399(50)09172-

The electroreduction of 6-trimethylsilyl-6-hepten-2-one afforded cis-1- methyl-3-trimethylsilyl cyclohexanol, and γ-trimethylsilyl alcohols were yielded as the intermolecular coupling products when the cathodic reduction of ketones was carried out in the presence of unsaturated silanes.

Full text of DOI:10.1016/00404-0399(50)09172-

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