1135-59-7Relevant academic research and scientific papers
Antimalarial activity of novel 1,2,5,6-tetraoxacycloalkanes and 1,2,5-trioxacycloalkanes
Kim, Hye-Sook,Begum, Khurshida,Ogura, Naoki,Wataya, Yusuke,Nonami, Yuji,Ito, Toyonari,Masuyama, Araki,Nojima, Masatomo,McCullough, Kevin J.
, p. 1957 - 1961 (2003)
Photooxygenation of 2-phenylnorbornene 1 in the presence of 30% aqueous hydrogen peroxide afforded 1,2-bishydroperoxide 3, which could be cycloalkylated on treatment with silver oxide and a 1,ω-diiodoalkane to provide the tricyclic peroxides 12. Trimethyl
Synthesis, crystal structure and antimalarial activity of novel 1,2,5,6-tetraoxacycloalkanes from 2,3-dihydroperoxy-2-phenylnorbornane
McCullough, Kevin J.,Nonami, Yuji,Masuyama, Araki,Nojima, Masatomo,Kim, Hye-Sook,Wataya, Yusuke
, p. 9151 - 9155 (2007/10/03)
Photooxygenation of 2-phenylnorbornene 1 in the presence of 30% aqueous hydrogen peroxide in acetonitrile afforded the labile 1,2-bis-hydroperoxide 3 which could be cycloalkylated to provide the tricyclic peroxides 5, albeit in low yield, on treatment wit
Preparation and Reactivities of Hexakisacetonitrile Iron(III) Perchlorate and Related Complexes as Strong Oxidizing Reagents
Kotani,Eiichi,Kobayashi, Shigeki,Ishii, Yoko,Tobinaga, Seisho
, p. 4281 - 4291 (2007/10/02)
The iron(III) complexes Fe(S)6(ClO4)3, S=solvent, were prepared from Fe(H2O)6(ClO4)3 in the donor solvents.Reactions of alkylbenzenes with Fe(AN)6(ClO4)3 (AN=acetonitrile) were explored because the AN complex has the highest formal redox potential, E0=1.73 V vs.SCE, among these complexes.Oxidation of the primary alkylbenzenes by the iron(III) AN complex gave the corresponding acetamides (Table II).Oxidation of the secondary alkylbenzenes, namely, cumene, 2-phenylbutane, and 2-exo-phenylnorbornane, afforded the corresponding acetates and acetamides (Charts 2 and 3), consuming over 4-mol eq of reagent.Reactions of p-xylene and hexamethylbenzene with Fe(CH2=CHCN)6(ClO4)3 also yielded the amides 31a and 31b.These results demonstrate the applicability of the iron(III) AN complexes as a powerful reagent to oxidize organic substrates which have onset potentials of anodic current of ca. 2.0 V vs.SCE.Keywords - oxidation; primary alkylbenzene; secondary alkylbenzene; oxidizing reagent; iron(III) perchlorate solvate; hexakisacetonitrile iron(III) perchlorate; hexakisacrylonitrile iron(III) perchlorate
