1135-72-4

Basic information

• Product Name: 1-(hydroxy-phenyl-methyl)cyclohexan-1-ol
• Synonyms: 1-(hydroxy-phenyl-methyl)cyclohexan-1-ol
• CAS NO: 1135-72-4
• Molecular Formula: C₁₃H₁₈O₂
• Molecular Weight: 0
• Mol File: 1135-72-4.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 350.8°Cat760mmHg
• Flash Point: 167.1°C
• Appearance: /
• Density: 1.156g/cm³
• Vapor Pressure: 1.6E-05mmHg at 25°C
• Refractive Index: 1.585
• CAS DataBase Reference: 1-(hydroxy-phenyl-methyl)cyclohexan-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(hydroxy-phenyl-methyl)cyclohexan-1-ol(1135-72-4)
• EPA Substance Registry System: 1-(hydroxy-phenyl-methyl)cyclohexan-1-ol(1135-72-4)

Safety Data

• Hazardous Substances Data: 1135-72-4(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Tetrahedron Letters, 34, p. 2311, 1993 DOI: 10.1016/S0040-4039(00)77601-5

InChI:InChI=1/C13H18O2/c14-12(11-7-3-1-4-8-11)13(15)9-5-2-6-10-13/h1,3-4,7-8,12,14-15H,2,5-6,9-10H2

Upstream product

• 1195776-87-4 1-(methoxymethoxyphenyl)methylcyclohexanol 
• 34877-64-0 2-phenyl-1-oxaspiro[2,5]octane 
• 947-19-3 1-hydroxycyclohexyl phenyl ketone 
• 108-94-1 cyclohexanone 
• 100-52-7 benzaldehyde 
• 412346-08-8 8,16-diphenyl-7,15-dioxa-dispiro[5.2.5.2]hexadecane-8,16-diol 
• 1135-71-3 (1-chlorocyclohexyl)(phenyl)methanone 
• 712-50-5 Cyclohexyl phenyl ketone 
• 4714-09-4 1-benzylcyclohexene 
• 1944-01-0 1-benzylcyclohexan-1-ol 
• 4410-75-7 (cyclohexylmethyl)benzene 

Downstream Products

• 947-19-3 1-hydroxycyclohexyl phenyl ketone 
• 65-85-0 benzoic acid 

Relevant articles and documents

Pincerlike molybdenum complex and preparation method thereof, catalytic composition and application thereof, and alcohol preparation method

The invention discloses a clamp-type molybdenum complex, a preparation method, a corresponding catalyst composition and application. The method comprises the steps: obtaining 9 molybdenum complexes with different structures through coordination reaction of 2-(substituent ethyl)-(5, 6, 7, 8-tetrahydroquinolyl) amine and a corresponding carbonyl molybdenum metal precursor; and catalyzing a ketone compound transfer hydrogenation reaction through a molybdenum complex to generate 40 alcohol compounds. The preparation method of the molybdenum complex is simple, high in yield and good in stability. For a transfer hydrogenation reaction of ketone, the molybdenum-based catalytic system has high catalytic activity and small molybdenum loading capacity, is used for production of aromatic and aliphatic alcohols, and has the advantages of simple method, small environmental pollution and high yield.

Direct metalation of methoxymethyl arylmethyl ethers: A tin-free approach to the generation of α-alkoxyalkoxy-substituted aryllithiums

The generation of a series of α-methoxymethoxy-substituted arylmethyllithiums was achieved by direct metalation of the corresponding arylmethyl methoxymethyl ethers. While the effect of substituents at the benzylic position is straightforward, substituent

Samarium Dibromide, an Efficient Reagent for the Pinacol Coupling Reactions.

The preparation of SmBr2 from Sm2O3 is described.This samarium (II) compound is a powerful one electron reductant able to very efficiently mediate pinacolic couplings.Cross couplings are effective in some cases, for example a chiral diol can be obtained from benzophenone and camphor.Intramolecular pinacolization of a diketone has been performed.