113641-96-6

Basic information

• Product Name: Silane, [[1-(2-bromophenyl)ethenyl]oxy]trimethyl-
• CAS NO: 113641-96-6
• Molecular Formula: C11H15BrOSi
• Molecular Weight: 271.229
• Mol File: 113641-96-6.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Silane, [[1-(2-bromophenyl)ethenyl]oxy]trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [[1-(2-bromophenyl)ethenyl]oxy]trimethyl-(113641-96-6)
• EPA Substance Registry System: Silane, [[1-(2-bromophenyl)ethenyl]oxy]trimethyl-(113641-96-6)

Safety Data

• Hazardous Substances Data: 113641-96-6(Hazardous Substances Data)

Upstream product

• 27607-77-8 trimethylsilyl trifluoromethanesulfonate 
• 2142-69-0 2-bromophenyl methyl ketone 
• 75-77-4 chloro-trimethyl-silane 

Downstream Products

• 1186503-77-4 1-(2-bromophenyl)cyclopropanol 
• 99391-09-0 C₁₄H₁₀BrNO₂ 
• 113642-10-7 4-(2-o-bromo-β-hydroxyphenetyl)azetidin-2-one 
• 17983-63-0 2'-(trimethylsilyl)acetophenone 
• 99391-16-9 C₁₇H₂₀BrNO₂Si 
• 86951-26-0 4-(o-bromobenzoylmethyl)azetidin-2-one 
• 99233-20-2 α-hydroxy-2-bromoacetophenone 

Relevant articles and documents

Palladium-Catalyzed [5 + 2] Annulation of Vinylethylene Carbonates with Barbiturate-Derived Alkenes

A palladium/XantPhos-catalyzed [5 + 2] annulation of VECs with electron-deficient alkenes having an isolated carbon-carbon double bond has been developed to afford spirobarbiturate-tetrahydrooxepines. This study provides an expedient assembly of biologically interesting spirobarbiturate-tetrahydrooxepines. The easy scalability and versatile transformability of the reaction products were also exhibited.

Synthesis of β-Amino Ketones by Addition of Aryl Methyl Ketones to Sulfinimines: Application to the Total Synthesis of HPA-12, Norsedamine, and Sedamine

Synthesis of β-sulfinamido ketones was accomplished by the addition of silyl enol ethers derived from arylmethyl ketones to chiral sulfinimines in excellent yield and selectivity. Application of the formed β-amino substituted ketones is exemplified in the total synthesis of sphingolipid HPA-12 and the sedamine alkaloids.

Synthesis of 3-Fluoropyridines via Photoredox-Mediated Coupling of α,α-Difluoro-β-iodoketones with Silyl Enol Ethers

A method for the synthesis of diversely substituted 3-fluoropyridines from two ketone components is described. The reaction involves photoredox coupling of α,α-difluoro-β-iodoketones with silyl enol ethers catalyzed by fac-Ir(ppy)3 under blue LED irradiation with subsequent one-pot condensation with ammonium acetate. Based on cyclic voltammetry studies, it was determined that α,α-difluoro-β-iodoketones are reduced notably easier compared to 2,2,2-trifluoro-1-iodoethane, which may be ascribed to the influence of the carbonyl group.