113697-57-7

Basic information

• Product Name: ETHYL 4-(4-METHOXYPHENYL)-6-METHYL-2-THIOXO-1,2,3,4-TETRAHYDRO-5-PYRIMIDINECARBOXYLATE
• Synonyms: ETHYL 4-(4-METHOXYPHENYL)-6-METHYL-2-THIOXO-1,2,3,4-TETRAHYDRO-5-PYRIMIDINECARBOXYLATE;ETHYL 4-(4-METHOXYPHENYL)-6-METHYL-2-THIOXO-1,2,3,4-TETRAHYDROPYRIMIDINE-5-CARBOXYLATE;ethyl 4-(4-methoxyphenyl)-6-methyl-2-sulfanylidene-1,2,3,4-tetrahydropyrimidine-5-carboxylate
• CAS NO: 113697-57-7
• Molecular Formula: C₁₅H₁₈N₂O₃S
• Molecular Weight: 306.38
• Mol File: 113697-57-7.mol
• Article Data: 106

Chemical Properties

• Appearance: /
• CAS DataBase Reference: ETHYL 4-(4-METHOXYPHENYL)-6-METHYL-2-THIOXO-1,2,3,4-TETRAHYDRO-5-PYRIMIDINECARBOXYLATE(CAS DataBase Reference)
• NIST Chemistry Reference: ETHYL 4-(4-METHOXYPHENYL)-6-METHYL-2-THIOXO-1,2,3,4-TETRAHYDRO-5-PYRIMIDINECARBOXYLATE(113697-57-7)
• EPA Substance Registry System: ETHYL 4-(4-METHOXYPHENYL)-6-METHYL-2-THIOXO-1,2,3,4-TETRAHYDRO-5-PYRIMIDINECARBOXYLATE(113697-57-7)

Safety Data

• Hazardous Substances Data: 113697-57-7(Hazardous Substances Data)

Upstream product

• 14202-31-4 4-methoxybenzaldehyde-1,1-diacetate 
• 141-97-9 ethyl acetoacetate 
• 17356-08-0 thiourea 
• 123-11-5 4-methoxy-benzaldehyde 
• 1147550-11-5 ammonium thiocyanate 
• 105-13-5 4-Methoxybenzyl alcohol 
• 100-52-7 benzaldehyde 
• 109086-77-3 2-(4'-methoxyphenyl)perhydro-1,3-oxazine 

Downstream Products

• 154867-09-1 ethyl 5-(4-methoxyphenyl)-2-(4-methoxyphenylmethylene)-7-methyl-3-oxo-2,3-dihydro-5H-thiazolo<3,2-a>pyrimidine-6-carboxylate 
• 1122513-45-4 ethyl 1-formyl-6-(4-methoxyphenyl)-4-methyl-2-thioxo-1,2,3,4-tetrahydropyrimidine-5-carboxylate 
• 300723-21-1 C₂₄H₂₂N₂O₄S 
• 3774-99-0 5-benzylidene-2,4-thiazolidinedione 
• 799266-38-9 ethyl 3-methyl-5-(p-methoxyphenyl)-7-methyl-5H-thiazolo[3,2-a]pyrimidine-6-carboxylate 
• 1301742-02-8 C₃₀H₃₂N₄O₆S 
• 1408332-02-4 4-(4-methoxyphenyl)-5-(sulfadiazinyl-amido)-6-methyl-1,2,3,4-tetrahydropyrimidine-2-thiones 
• 1449415-03-5 C₂₃H₁₈N₄O₃S 
• 113697-60-2 ethyl 5-(4-methoxyphenyl)-7-methyl-3-oxo-2,3-dihydro-5H-thiazolo<3,2-a>pyrimidine-6-carboxylate 

Relevant articles and documents

Efficient Ce(NO3)3·6H2O-catalyzed solvent-free synthesis of 3,4-dihydropyrimidin-2(1H)-ones

Cerium(III) nitrate hexahydrate efficiently catalyzes the three-component Biginelli reaction under solvent-free conditions of an aldehyde, a β-keto ester or β-diketone and urea or thiourea to afford the corresponding 3,4-dihydropyrimidin-2(1H)-ones or -th

FeCl36H2O-Catalyzed Conversion of acylals to dihydropyrimidinones under microwave conditions: A new procedure for the Biginelli reaction

FeCl36H2O efficiently catalyzed the three-component condensation reaction of acylals, ethyl acetoacetate, and urea or thiourea to afford the corresponding 3,4-dihydropyrimidin-2(1H)-ones in good yields under solvent-free and microwav

Calix[8]arene sulfonic acid catalyzed three-component reaction for convenient synthesis of 3,4-dihydropyrimidin-2(1H)-ones/thiones under ultrasonic irradiation

In this work, the catalytic activity of calix[8]arene sulfonic acid was successfully investigated for the famous Biginelli reaction. Under ultrasonic irradiation, calix[8]arene sulfonic acid could efficiently catalyzed the three-component reaction of alde

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Iron (III) phosphate dihydrate - Catalyzed one-pot synthesis of dihydropyrimidinones and thiones: An improved procedure for the Biginelli reaction

A fast and high yielding one-pot synthesis of 3,4-dihydropyrimidin-2(1H)- ones with various aliphatic and aromatic aldehydes using FePO 4.2H2O as heterogeneous catalyst was carried out in acetonitrile.

Bismuth subnitrate catalyzed efficient synthesis of 3,4-dihydropyrimidin- 2(1H)-ones: An improved protocol for the Biginelli reaction

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Tetrabutylammonium hexatungstate [TBA]2[W6O 19], an isopolytungstate, was found to be a highly efficient and recyclable heterogeneous catalyst for Biginelli reaction of ethyl acetoacetate, an aryl aldehyde, and urea or thi

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Xanthan sulfuric acid (XSA) is employed as a recyclable catalyst for the synthesis of 3,4-dihydropyrimidin-2(1H)-ones. These syntheses were performed via a one-pot, threecomponent condensation of aldehydes, amines, and urea/thiourea under solvent-free con

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A facile, efficient, and environmentally benign procedure for the synthesis of 3,4-dihydropyrimidin-2-(1H)-ones via the cyclocondensation reaction of aromatic aldehyde, ethyl acetoaceate, and urea catalyzed by CsF-Celite was developed. This environmentall

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3,4-Dihydropyrimidin-2(1H)-ones and their sulfur analogues are efficiently synthesized by the three-component condensation of β-dicarbonyl compounds, aromatic and aliphatic aldehydes, and urea or thiourea in the presence of catalytic amounts of silica sul

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Trimethylsilyl chloride (TMSCl) was used as a Lewis acid to efficiently perform one-pot, three-components, Biginelli condensation reactions of aldehydes, 1,3-dicarbonyl compounds, and urea or thiourea. This resulted in simple one-pot synthesis of the corr

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Sc(III) triflate efficiently catalyzes the three-component condensation reaction of an aldehyde, a β-ketoester, and urea in refluxing acetonitrile to afford the corresponding 3,4-dihydropyrimidin-2(1H)-ones in excellent yields. The catalyst can be recover

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