113772-13-7

Basic information

• Product Name: METHYL 2-CYANO-2-(2-NITROPHENYL)ACETATE
• Synonyms: METHYL 2-CYANO-2-(2-NITROPHENYL)ACETATE;α-Cyano-2-nitro-benzeneacetic Acid Methyl Ester
• CAS NO: 113772-13-7
• Molecular Formula: C₁₀H₈N₂O₄
• Molecular Weight: 220.18
• Product Categories: Aromatics
• Mol File: 113772-13-7.mol
• Article Data: 5

Chemical Properties

• Melting Point: 58-59°C
• Boiling Point: 393.2°Cat760mmHg
• Flash Point: 191.6°C
• Appearance: /
• Density: 1.336g/cm³
• Vapor Pressure: 2.17E-06mmHg at 25°C
• Refractive Index: 1.56
• Storage Temp.: Refrigerator
• CAS DataBase Reference: METHYL 2-CYANO-2-(2-NITROPHENYL)ACETATE(CAS DataBase Reference)
• NIST Chemistry Reference: METHYL 2-CYANO-2-(2-NITROPHENYL)ACETATE(113772-13-7)
• EPA Substance Registry System: METHYL 2-CYANO-2-(2-NITROPHENYL)ACETATE(113772-13-7)

Safety Data

• Hazard Codes: Xn:Harmful
• Statements: R20/21/22:Harmful by inhalation, in contact with skin and if swallowed.
• Safety Statements: S36/37:Wear suitable protective clothing and gloves.
• Hazardous Substances Data: 113772-13-7(Hazardous Substances Data)

Usage

Chemical Properties

Light Yellow Solid

Uses

Methyl Cyano(2-nitrophenyl)acetate (cas# 113772-13-7) is a compound useful in organic synthesis.

InChI:InChI=1/C10H8N2O4/c1-16-10(13)8(6-11)7-4-2-3-5-9(7)12(14)15/h2-5,8H,1H3

Upstream product

• 1493-27-2 ortho-nitrofluorobenzene 
• 105-34-0 methyl 2-cyanoacetate 
• 1643377-91-6 methyl 2-fluoro-2-(2-nitrophenyl)acetate 
• 75-05-8 acetonitrile 

Downstream Products

• 614755-48-5 2-cyano-2-(2-nitro-phenyl)-pent-4-enoic acid methyl ester 
• 5719-08-4 4-chloro-1H-pyrimido[4,5-b]indole 
• 113772-15-9 methyl 2-amino-1-methylindole-3-carboxylate 
• 67282-55-7 1-methoxy-1H-indole-3-carbaldehyde 
• 724706-20-1 4-ethyl 1-methyl 2-cyano-2-(2-nitrophenyl)succinate 
• 113772-14-8 methyl 2-amino-1H-indole-3-carboxylate 

Relevant articles and documents

TfOH-Promoted Decyanative Cyclization toward the Synthesis of 2,1-Benzisoxazoles

A novel solvent-free, TfOH-promoted decyanative cyclization approach for the synthesis of 2,1-benzisoxazoles has been developed. The reactions are complete instantly at room temperature and result in the formation of the desired 2,1-benzisoxazoles in a 34-97% isolated yield.

Efficient total syntheses of phytoalexin and (±)-paniculidine B and C based on the novel methodology for the preparation of 1-methoxyindoles

A general route to 2-unsubstituted-1-methoxyindoles, based on our methodology for the synthesis of 1-methoxyindoles, is reported. This synthesis renders accessibility to a variety of natural products possessing the said skeleton. A direct synthesis of phy

Syntheses of Functionalised Pyridoindoles

Two complementary routes for the synthesis of highly functionalised pyridoindoles are described, starting from the readily available 2-amino-3-cyano-1-(4-methoxybenzyl)tetrahydroindole and methyl 2-aminoindole-3-carboxylate, respectively.The use of