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113812-13-8

N1,N4,N9,N12-tetra(p-toluenesulfonyl)-4,9-diaza-1,12-diaminododecane is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 113812-13-8 Structure

  • Basic information

    1. Product Name: N1,N4,N9,N12-tetra(p-toluenesulfonyl)-4,9-diaza-1,12-diaminododecane
    2. Synonyms: N1,N4,N9,N12-tetra(p-toluenesulfonyl)-4,9-diaza-1,12-diaminododecane
    3. CAS NO:113812-13-8
    4. Molecular Formula:
    5. Molecular Weight: 819.101
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 113812-13-8.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: N1,N4,N9,N12-tetra(p-toluenesulfonyl)-4,9-diaza-1,12-diaminododecane(CAS DataBase Reference)
    10. NIST Chemistry Reference: N1,N4,N9,N12-tetra(p-toluenesulfonyl)-4,9-diaza-1,12-diaminododecane(113812-13-8)
    11. EPA Substance Registry System: N1,N4,N9,N12-tetra(p-toluenesulfonyl)-4,9-diaza-1,12-diaminododecane(113812-13-8)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 113812-13-8(Hazardous Substances Data)

113812-13-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 113812-13-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,3,8,1 and 2 respectively; the second part has 2 digits, 1 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 113812-13:
(8*1)+(7*1)+(6*3)+(5*8)+(4*1)+(3*2)+(2*1)+(1*3)=88
88 % 10 = 8
So 113812-13-8 is a valid CAS Registry Number.

113812-13-8Relevant articles and documents

T7 RNA polymerase activation and improvement of the transcriptional sequencing by polyamines

Iwata, Masaaki,Izawa, Masaki,Sasaki, Nobuya,Nagumo, Yoko,Sasabe, Hiroyuki,Hayashizaki, Yoshihide

, p. 2185 - 2194 (2007/10/03)

We examined the possibility to improve the effectiveness of the in vitro transcription system using T7 RNA polymerase by coexistence with organic bases. The effect of the additives was evaluated by measuring the amount of RNA products in comparison with t

Thermal removal of BOC-protecting groups during preparation of open-chain polyamines

Krakowiak, Krzysztof E.,Bradshaw, Jerald S.

, p. 3999 - 4004 (2007/10/03)

Per-N-tosylated 3,8-diaza-1,10-decanediamine (9), 4,9-diaza-1,12-dodecanediamine (spermine) (10) and 3,6,9,14,17,20-hexaaza-1,22-docosanediamine (11) were prepared by treating mono-BOC-protected, per-N-tosylated 1,2-ethanediamine (5), 1,3-propanediamine (6) and triethylenetetraamine (7), respectively, with 1,4-dibromobutane and removing the BOC-protecting groups at 100-120°C.

Design and Synthesis of Macromonocyclic Polyamines Composed of Natural Methylene Arrays

Iwata, Masaaki,Kuzuhara, Hiroyoshi

, p. 198 - 210 (2007/10/02)

A general synthetic method applicable to acyclic and cyclic polyamines was developed.The methodology was exemplified by systematical synthesis of twelve macromonocyclic polyamines, 1 (N4) through 12 (N8), composed of the combination of four natural polyamine segments, spermidine, spermine, thermine, and thermospermine.These twelve designed macrocycles are exhausted numbers of possible structures defined by three arbitrarily chosen criteria concerning with methylene chain arrays and nitrogen content (four to eight).The common elements of the structural characteristics were analyzed and were found to be reduced to readily available three classes of simple N,N'-ditosylalkanediamines derived from diamines and triamine.Nitrogen content was increased systematically through the reaction of N,N'-ditosylalkanediamine with one of three ω-phthalimidated electrophiles followed by regeneration of the same functionality at symmetrical both terminals as the starting materials via a series of transformation reaction, in excellent yields.Tractable formamide intermediate profits the facile synthesis of acyclic polyamines with long chains.Cyclization was achieved, under high dilution conditions, through the reaction of α,ω-bis(tosylamide) with α,ω-ditosylates in DMF in the presence of cesium carbonate.The cyclization occurred in practical synthetic yields even in the formation of multi-membered ring when the shorter electrophile and the longest α,ω-bis(tosylamide) reacted.

FIFTY-TWO MEMBERED MACROMONOCYCLIC POLYAMINE POSSESSING TWELVE NITROGEN ATOMS IN THE RING: CYCLIC SPERMINE TETRAMER

Iwata, Masaaki,Kuzuhara, Hiroyoshi

, p. 1009 - 1014 (2007/10/02)

By the reaction of 1,4-dibromobutane with forty-eight membered acyclic polyamine in the presence of cesium carbonate in DMF, cyclic spermine (or thermospermine) tetramer was prepared in 72percent yield.

Synthetic polyamine Analogues as Antineoplastics

Bergeron, Raymond J.,Neims, Allen H.,McManis, James S.,Hawthorne, Thomas R.,Vinson, John R. T.,et al.

, p. 1183 - 1190 (2007/10/02)

In this paper, we report on the synthesis and biological activity of a number of N-alkylated spermine compounds.The dialkylspermines N1,N12-dimethylspermine (DMSPM-2), N1, N12-diethylspermine (DESPM-3), and Nsu

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