113815-39-7

Basic information

• Product Name: (1,2,2-trichloro-ethyl)-benzene
• CAS NO: 113815-39-7
• Molecular Weight: 209.503
• Mol File: 113815-39-7.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: (1,2,2-trichloro-ethyl)-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (1,2,2-trichloro-ethyl)-benzene(113815-39-7)
• EPA Substance Registry System: (1,2,2-trichloro-ethyl)-benzene(113815-39-7)

Safety Data

• Hazardous Substances Data: 113815-39-7(Hazardous Substances Data)

Upstream product

• 79-01-6 Trichloroethylene 
• 79692-77-6 (phenylazo)diphenylmethanol 
• 140-10-3 (E)-3-phenylacrylic acid 
• 35115-76-5 2,3-dichloro-3-phenyl-propionic acid 
• 622-25-3 1-(2-chlorovinyl)benzene 
• 100-42-5 styrene 
• 100-52-7 benzaldehyde 
• 6943-57-3 (phenylazo)diphenylmethyl acetate 
• 574-61-8 benzophenone N-phenylhydrazone 
• 2612-36-4 2,2-dichloro-1-phenylethanol 
• 4110-77-4 (E)-β-chlorostyrene 
• 52147-97-4 trans 2-phenylethenesulfonyl chloride 

Downstream Products

• 706-93-4 Phenylpentachloroethane 

Relevant articles and documents

vic-Dichlorination of olefins with sodium chlorite, Mn(acac)3, and moist alumina in dichloromethane

Aliphatic, alicyclic, and aromatic alkenes underwent smooth vicdichlorination upon treatment with a reagent combination of NaClO2, Mn(acac)3 catalyst, and chromatographic neutral alumina preloaded with a small amount of water in dichloromethane under mild conditions.

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Use of a fluorous bridge for diffusion controlled uptake of molecular chlorine in chlorine addition to alkenes

Fluorous solvent was used for passive transport of molecular chlorine from one side of the U-tube to the other, where addition of chlorine to alkenes was quantitative and diffusion controlled.

Reaction of α,β-Unsaturated Carboxylic Acids with Manganese(III) Acetate in the Presence of Chloride Ion

The reaction of 3-phenylpropenoic acids with manganese(III) acetate - Cl- complex yielded 1,2,2-trichloro-1-phenylethanes, 1-acetoxy-2,2-dichloro-1-phenylethanes, and 2,2-dichloro-1-phenylethanols. (E)-2,3-Diphenylpropenoic acids gave 2,2-dichloro-1,2-diphenylethanones and 2-acetoxy-1,2-diphenylethanones. 3,3-Diphenylpropenoic acids yielded 2,2-dichloro-1,1-diphenylethenes, 1-acetoxy-2,2-dichloro-1,1-diphenylethanes, 2,2-dichloro-1,1-diphenyl-1-ethanols, and 2-hydroxy-2,2-diphenylethanal.Fluorenylideneacetic acid gave 9-chloro-9-(dichloromethyl)fluorene, 9-acetoxy-9-(dichloromethyl)fluorene, and 9-fluorenone. 1-Cyclohexenecarboxylic acid yielded 1,2-dichlorocyclohexanecarboxylic acid and 1-acetoxy-2-chlorocyclohexanecarboxylic acid.The reaction can be explained in terms of a free-radical mechanism involving manganese(III) acetate - Cl- complexation, addition of Cl. radical, decarboxylation, and the oxidation of chloroethenes which are the reaction intermediates.