114091-81-5Relevant articles and documents
STEREOSELECTIVE ADDITION OF A NOVEL, ENANTIOMERICALLY PURE VINYLLITHIUM REAGENT TO PROCHIRAL CARBONYL COMPOUNDS
Mahler, Hellmut,Braun, Manfred
, p. 5145 - 5148 (1987)
The vinyllithium reagent (S)-3, generated from the alkene 6 by bromine/lithium exchange, reacts stereoselectively with prochiral carbonyl compounds.Debromination of the adducts 4/8 affords the (Z)-olefins 11/12, which can be cleaved by ozonolyzis.