114140-91-9Relevant academic research and scientific papers
A General and Useful Copper(II)-promoted Iodofunctionalization of Unsaturated Systems
Barluenga, Jose,Rodriguez, Miguel A.,Campos, Pedro J.,Asensio, Gregorio
, p. 1491 - 1492 (1987)
A mixture of iodine and CuO*HBF4 reacts stereospecifically with olefins in the presence of a wide variety of nucleophiles (NaNO2, NaSO2Ar, NaI, Et3SiH, MeOPh and H2O) to give the corresponding 2-functionalized iodo compounds; the same reagents also cause iodofunctionalization of 1,3-dienes and acetylenes.
An Efficient Method for the Copper(II)-promoted Stereoselective Iodofunctionalization of Alkenes
Barluenga, Jose,Rodriguez, Miguel A.,Campos, Pedro J.
, p. 2807 - 2809 (2007/10/02)
A mixture of iodine and CuO*HBF4 reacts stereoselectively with alkenes in the presence of a wide variety of nucleophiles (water, MeOH, HCO2H, AcOH, EtCOOH, NaNO2, KSCN, NaSO2Ar, LiCl, LiBr, NaI, Et3SiH, and MeOPh) to give the corresponding 2-functionalized iodo compounds.A regio chemistry study is also reported.
