Journal of the Chemical Society. Chemical communications p. 1491 - 1492 (1987)
Update date:2022-08-02
Topics:
Barluenga, Jose
Rodriguez, Miguel A.
Campos, Pedro J.
Asensio, Gregorio
A mixture of iodine and CuO*HBF4 reacts stereospecifically with olefins in the presence of a wide variety of nucleophiles (NaNO2, NaSO2Ar, NaI, Et3SiH, MeOPh and H2O) to give the corresponding 2-functionalized iodo compounds; the same reagents also cause iodofunctionalization of 1,3-dienes and acetylenes.
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