1143-74-4

Basic information

• Product Name: N-Benzoyl-N-(o-tolyl)-hydroxylamine
• Synonyms: N-Benzoyl-N-(o-tolyl)-hydroxylamine;N-(2-Methylphenyl)benzenecarbohydroxamic acid;N-(2-Methylphenyl)benzohydroxamic acid;N-(o-Tolyl)-N-hydroxybenzamide;N-Hydroxy-N-(2-methylphenyl)benzamide;N-o-Tolylbenzohydroxamic acid
• CAS NO: 1143-74-4
• Molecular Formula: C₁₄H₁₃NO₂
• Molecular Weight: 0
• Mol File: 1143-74-4.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 380.2°C at 760 mmHg
• Flash Point: 183.8°C
• Appearance: /
• Density: 1.234g/cm³
• Vapor Pressure: 1.85E-06mmHg at 25°C
• Refractive Index: 1.651
• CAS DataBase Reference: N-Benzoyl-N-(o-tolyl)-hydroxylamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-Benzoyl-N-(o-tolyl)-hydroxylamine(1143-74-4)
• EPA Substance Registry System: N-Benzoyl-N-(o-tolyl)-hydroxylamine(1143-74-4)

Safety Data

• Hazardous Substances Data: 1143-74-4(Hazardous Substances Data)

Usage

Purification Methods

Recrystallise the hydroxylamine from aqueous EtOH. [Beilstein 15 III 8, 15 IV 7.]

InChI:InChI=1/C14H13NO2/c1-11-7-5-6-10-13(11)15(17)14(16)12-8-3-2-4-9-12/h2-10,17H,1H3

Upstream product

• 98-88-4 benzoyl chloride 
• 611-22-3 N-(o-tolyl)hydroxylamine 
• 611-23-4 2-nitrosotoluene 
• 100-52-7 benzaldehyde 
• 88-72-2 1-methyl-2-nitrobenzene 
• 90985-20-9 N,O-dibenzoyl-N-o-tolyl-hydroxylamine 

Downstream Products

• 10286-86-9 N-(2-chloro-6-methylphenyl)benzamide 
• 131740-39-1 {C₆H₅CON(CH₃C₆H₄)O}{O(O)CCH₂C(O)O}B 
• 131740-30-2 {C₆H₅CON(CH₃C₆H₄)O}{OC₆H₄C(O)O}B 
• 131740-35-7 {C₆H₅CON(CH₃C₆H₄)O}{O(O)CC(O)O}B 
• 74560-93-3 cis-dichloro bis(N-2-methylphenylbenzohydroxamato)tin(IV) 
• 87037-74-9 dibutylbis(N-2-methylphenylbenzohydroxamato)tin(IV) 
• 81923-16-2 diphenylbis(N-2-methylphenylbenzohydroxamato)tin(IV) 
• 84020-91-7 (C₆H₅)3SnON(CH₃C₆H₄)CO(C₆H₅) 
• 78379-23-4 BF₂(C₆H₅CON(O)C₆H₄CH₃) 
• 105517-61-1 OHB(C₆H₅)(OCNO(C₆H₅)(CH₃C₆H₄)) 
• 65-85-0 benzoic acid 
• 611-22-3 N-(o-tolyl)hydroxylamine 

Relevant articles and documents

N-HETEROCYCLIC CARBENE (NHC) CATALYZED SYNTHESIS OF HYDROXAMIC ACIDS

A process for preparing hydroxamic acids is provided. The process comprises reacting an aldehyde with a nitroso compound in the presence of a N-heterocyclic carbene (NHC) catalyst.

Facile Transfer-Reduction of Nitroarenes to N-Arylhydroksylamines with Hydrazine in the Presence of Raney Nickel

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