114303-65-0

Basic information

• Product Name: Benzene, 4-bromo-1-methoxy-2-(2-propenyl)-
• CAS NO: 114303-65-0
• Molecular Formula: C10H11BrO
• Molecular Weight: 227.101
• Mol File: 114303-65-0.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Benzene, 4-bromo-1-methoxy-2-(2-propenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 4-bromo-1-methoxy-2-(2-propenyl)-(114303-65-0)
• EPA Substance Registry System: Benzene, 4-bromo-1-methoxy-2-(2-propenyl)-(114303-65-0)

Safety Data

• Hazardous Substances Data: 114303-65-0(Hazardous Substances Data)

Upstream product

• 607-99-8 2,4,6-tribromoanisole 
• 80866-82-6 5-bromo-2-methoxy-benzyl alcohol 
• 3536-96-7 vinylmagnesium chloride 
• 184970-28-3 4-bromo-2-(bromomethyl)-1-methoxybenzene 
• 106-41-2 4-bromo-phenol 
• 182056-39-9 2-bromo-4-iodo-1-methoxybenzene 
• 106-95-6 allyl bromide 
• 25244-30-8 4-(allyloxy)bromobenzene 
• 13997-74-5 2-allyl-4-bromophenol 
• 74-88-4 methyl iodide 
• 21702-84-1 2,4-dibromoanisole 
• 77-78-1 dimethyl sulfate 
• 1465765-08-5 C₁₇H₁₅BrO₃ 

Downstream Products

• 261769-31-7 1-(3-allyl-4-methoxy-phenyl)-6-(tert-butyl-dimethyl-silanyloxy)-hexan-1-ol 
• 67483-48-1 3-allyl-4-methoxybenzaldehyde 
• 905562-85-8 3-allyl-4-methoxy-N,N-dimethylbenzamide 
• 68592-15-4 methylhonokiol 
• 1378871-34-1 4-methoxy-3-allyl-1-phenylboronic acid 
• 261769-32-8 6-(3-allyl-4-methoxy-phenyl)-6-methoxymethoxy-hexan-1-ol 
• 261769-33-9 6-(3-allyl-4-methoxy-phenyl)-6-methoxymethoxy-hexanal 
• 905562-52-9 3-(3-bromo-6-methoxyphenyl)propane-1,2-diol 

Relevant articles and documents

Regioselective Bromine/Magnesium Exchange for the Selective Functionalization of Polyhalogenated Arenes and Heterocycles

Using the bimetallic combination sBu2Mg?2 LiOR (R=2-ethylhexyl) in toluene enables efficient and regioselective Br/Mg exchanges with various dibromo-arenes and -heteroarenes under mild reaction conditions and provides bromo-substituted magnesiu

Selective formation of non-conjugated olefins by samarium(II)-mediated elimination/isomerization of allylic benzoates

Aromatic allylic benzoates can be selectively transformed to the corresponding benzoate eliminated olefin by the action of samarium diiodide. Depending on the substrate and the elimination conditions, high selectivity for the non-conjugated alkene product

A concise synthesis of 4′-O-methyl honokiol

A concise and protecting group free synthesis of the naturally occurring neolignan 4′-O-methyl honokiol is developed. The key biaryl bond is constructed by 1,2-addition of an aryl Grignard reagent to a dienone followed by rearrangement.