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114476-84-5 Usage

General Description

3-Chlorophenoxyacetyl chloride is a chemical compound with the formula C8H7Cl2O2. It is a colorless to pale yellow liquid that is used in the synthesis of the herbicide, 2,4-dichlorophenoxyacetic acid (2,4-D). 3-CHLOROPHENOXYACETYL CHLORIDE is an acyl chloride, which means it contains a functional group consisting of a carbonyl group attached to a chlorine atom. Acyl chlorides are commonly used as intermediates in the synthesis of various organic compounds, and 3-Chlorophenoxyacetyl chloride is no exception. It is a valuable chemical for the production of herbicides and pesticides, as well as pharmaceuticals and other industrial chemicals.

Check Digit Verification of cas no

The CAS Registry Mumber 114476-84-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,4,4,7 and 6 respectively; the second part has 2 digits, 8 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 114476-84:
(8*1)+(7*1)+(6*4)+(5*4)+(4*7)+(3*6)+(2*8)+(1*4)=125
125 % 10 = 5
So 114476-84-5 is a valid CAS Registry Number.
InChI:InChI=1/C8H6Cl2O2/c9-6-2-1-3-7(4-6)12-5-8(10)11/h1-4H,5H2

114476-84-5 Well-known Company Product Price

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  • Alfa Aesar

  • (L18427)  (3-Chlorophenoxy)acetyl chloride, 95%   

  • 114476-84-5

  • 1g

  • 1023.0CNY

  • Detail
  • Alfa Aesar

  • (L18427)  (3-Chlorophenoxy)acetyl chloride, 95%   

  • 114476-84-5

  • 5g

  • 4276.0CNY

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114476-84-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-(3-chlorophenoxy)acetyl chloride

1.2 Other means of identification

Product number -
Other names m-chlorophenoxyacetyl chloride

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:114476-84-5 SDS

114476-84-5Relevant articles and documents

Design and Synthesis of Novel 4-Hydroxyl-3-(2-phenoxyacetyl)-pyran-2-one Derivatives for Use as Herbicides and Evaluation of Their Mode of Action

Lei, Kang,Li, Pan,Yang, Xue-Fang,Wang, Shi-Ben,Wang, Xue-Kun,Hua, Xue-Wen,Sun, Bin,Ji, Lu-Sha,Xu, Xiao-Hua

, p. 10489 - 10497 (2019/10/02)

In order to develop a novel herbicide containing the β-triketone motif, a series of 4-hydroxyl-3-(2-phenoxyacetyl)-pyran-2-one derivatives were designed and synthesized. The bioassay results showed that compound II15 had good pre-emergent herbicidal activity even at a dosage of 187.5 g ha-1. Moreover, compound II15 showed a broader spectrum of weed control when compared with a commercial herbicide 2,4-dichlorophenoxyacetic acid (2,4-D), and displayed good crop safety to Triticum aestivum L. and Zea mays Linn. when applied at 375 g ha-1 under pre-emergence conditions, which indicated its great potential as a herbicide. More importantly, studying the molecular mode of action of compound II15 revealed that the novel triketone structure is a proherbicide of its corresponding phenoxyacetic acid auxin herbicide, which has a herbicidal mechanism similar to that of 2,4-D. The present work indicates that the 4-hydroxyl-3-(2-phenoxyacetyl)-pyran-2-one motif may be a potential lead structure for further development of novel auxin-type herbicides.

The synthesis of ethacrynic acid thiazole derivatives as glutathione S-transferase pi inhibitors

Li, Ting,Liu, Guyue,Li, Hongcai,Yang, Xinmei,Jing, Yongkui,Zhao, Guisen

, p. 2316 - 2322 (2012/05/07)

Glutathione S-transferase pi (GSTpi) is a phase II enzyme which protects cells from death and detoxifies chemotherapeutic agents in cancer cells. Ethacrynic acid (EA) is a weak GSTpi inhibitor. Structure modifications were done to improve the ability of EA to inhibit GSTpi activity. Eighteen EA thiazole derivatives were designed and synthesized. Compounds 9a, 9b and 9c with a replacement of carboxyl group of EA by a heterocyclic thiazole exhibited improvement over EA to inhibit GSTpi activity.

Biological Evaluation of some New Nitrophenoxy/Halophenoxyaeetyl/Propionyl-2-mercaptobenzothiazoles

Khare,Srivastava,Mukharya

, p. 627 - 628 (2007/10/03)

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