114493-18-4

Upstream product

• 22920-01-0 cis-2-methyl-2-carboxy-cyclohexane-1-acetic acid 
• 23667-58-5 (4aS)-6-methoxy-4a-methyl-(4ar,10ac)-2,3,4,4a,10,10a-hexahydro-1H-phenanthren-9-one 
• 79-37-8 oxalyl dichloride 
• 52782-05-5 (+/-)-1-methyl-cyclohexane-1r,2t-dicarboxylic acid-1-methyl ester 
• 22844-34-4 5-methyl-Δ³-trans-octalin-2-one 
• 26409-57-4 8a-methyl-1,3-dioxo-1,2,3,5,6,7,8,8a-octahydro-isoquinoline-4-carbonitrile 
• 86210-81-3 trans-2-carboxy-2-methylcyclohexaneacetic acid dimethyl ester 
• 100053-05-2 <2-Methyl-3-oxo-cycloheptanyl-(1)>-essigsaeure-methylester 
• 107153-81-1 (+/-)-(2c-methoxycarbonyl-2t-methyl-5-oxo-cyclohex-r-yl)-acetic acid methyl ester 
• 13351-29-6 cis-2H-1,3,3a,4,5,6,7,7a-octahydro-7a-methyl-2-indenone 
• 13025-91-7 (+-)-7a-methyl-cis-hexahydro-indan-1-one 
• 32042-69-6 (+/-)-(6c-carboxy-6t-methyl-cyclohex-3-en-r-yl)-acetic acid 
• 115387-18-3 3β,11α-diacetoxy-9-hydroxy-5α-ergost-22t-en-7-one 
• 61248-51-9 (3aS)-3a-methyl-trans-hexahydro-indan-2-one 

Downstream Products

• 91966-67-5 3-((1S)-2c-carboxy-2t-methyl-cyclohex-r-yl)-propionic acid 
• 86210-81-3 trans-2-carboxy-2-methylcyclohexaneacetic acid dimethyl ester 
• 22920-01-0 ((1S)-2c-carboxy-2t-methyl-cyclohex-r-yl)-acetic acid 
• 148260-33-7 ((1R)-2c-carboxy-2t-methyl-cyclohex-r-yl)-acetic acid 
• 86210-81-3 cis-2-carboxy-2-methylcyclohexaneacetic acid dimethyl ester 

Relevant academic research and scientific papers

Selective synthesis of glutaric acids from olefins

Six representative glutaric acids have been regio- and stereoselectively prepared from the corresponding olefins in 49 to 65% overall yields. α,α-Dichlorocyclopentanones, readily available from the olefins by three-carbon annelation, are transformed via chloro enol acetates to the glutaric acids.

Investigations on Reduction of 2-Carboxy-2-methylcyclohex-1-ylideneacetic Acid and Its Dimethyl Ester

The catalytic and chemical reductions of 2-carboxy-2-methylcyclohex-1-ylideneacetic acid (7)/its dimethyl ester (8) have been carried out as a model study.In these reduction studies, the mixture of cis- and trans-2-carboxy-2-methylcyclohexaneacetic acid (