114630-32-9Relevant academic research and scientific papers
Reactions of (M = Pd or Pt) with . Preparation of a Ph2PCH2SCH3-bridged palladium-rhodium complex
Anderson, Gordon K.
, p. 385 - 390 (2007/10/02)
When cis- and are allowed to react at ambient temperature cis- and are formed.By performing the reaction at -50 deg C the intermediate may be identified.In contrast reacts with to yield the mixed metal complex .
Platinum and rhodium complexes in which diphenylphosphino(methylthio)methane acts as a monodentate, chelated or bridging ligand
Anderson, Gordon K.,Kumar, Ravi
, p. 263 - 268 (2007/10/02)
Reaction of with Ph2PCH2SCH3 yields cis- which, on treatment with AgBF4, is converted to BF4, in which one of the ligands is chelated.With , cis- reacts to give the platinum(I) complex , which contains a platinum-platinum bond.The terminal chlorides may be replaced by iodide, but the complex is cleaved by carbon monoxide. reacts with Ph2PCH2SCH3 to produce , whereas with Ph2PCH2CH2SCH3 it yields .A ligand exchange reaction occurs between cis- and to give cis- and .
