95787-29-4

Upstream product

• 95787-31-8 {PtCl((C₆H₅)2PCH₂SCH₃)2}⁽¹⁺⁾*BF₄^(1-)={PtCl((C₆H₅)2PCH₂SCH₃)2}BF₄ 
• 12080-32-9 dichloro(1,5-cyclooctadiene)platinum(ll) 
• 13119-14-7 diphenylphosphino(methylthio)methane 
• 95787-32-9 Pt₂Cl₂((C₆H₅)2PCH₂SCH₃)2 
• 1641-69-6 [13C]Carbon monoxide 
• 56-34-8 tetraethylammonium chloride 

Downstream Products

• 95823-89-5 PtCl₂CO(C₆H₅)2PCH₂SCH₃ 
• 114630-32-9 Rh₂Cl₂(CO)2((C₆H₅)2PCH₂SCH₃)2 
• 95787-31-8 {PtCl((C₆H₅)2PCH₂SCH₃)2}⁽¹⁺⁾*BF₄^(1-)={PtCl((C₆H₅)2PCH₂SCH₃)2}BF₄ 
• 123455-00-5 (platinum(Cl)(Ph₂PCH₂SCH₃)2)(rhodium(Cl)2(CO)2) 

Relevant academic research and scientific papers

Platinum and rhodium complexes in which diphenylphosphino(methylthio)methane acts as a monodentate, chelated or bridging ligand

Reaction of with Ph2PCH2SCH3 yields cis- which, on treatment with AgBF4, is converted to BF4, in which one of the ligands is chelated.With , cis- reacts to give the platinum(I) complex , which contains a platinum-platinum bond.The terminal chlorides may be replaced by iodide, but the complex is cleaved by carbon monoxide. reacts with Ph2PCH2SCH3 to produce , whereas with Ph2PCH2CH2SCH3 it yields .A ligand exchange reaction occurs between cis- and to give cis- and .