115010-91-8Relevant academic research and scientific papers
DIELS-ALDER REACTIONS OF 1,3-DIENYLBORONATES AS A NEW ROUTE TO FUNCTIONALIZED CARBOCYCLES.
Vaultier, Michel,Truchet, Francoise,Carboni, Bertrand,Hoffmann, Reinhard W.,Denne, Ingrid
, p. 4169 - 4172 (1987)
Hydroboration of enynes with various hydroborating agents followed by refunctionalization at boron furnished 1,3-dienylboronates which undergo clean Diels-Alder addition to typical dienophiles.The resulting adducts contain an allylboronate functionality.Accordingly they add to aldehydes in a highly stereoselective fashion establishing the relative configuration at up to four stereogenic centers.
