Tetrahedron Letters p. 4169 - 4172 (1987)
Update date:2022-08-16
Topics:
Vaultier, Michel
Truchet, Francoise
Carboni, Bertrand
Hoffmann, Reinhard W.
Denne, Ingrid
Hydroboration of enynes with various hydroborating agents followed by refunctionalization at boron furnished 1,3-dienylboronates which undergo clean Diels-Alder addition to typical dienophiles.The resulting adducts contain an allylboronate functionality.Accordingly they add to aldehydes in a highly stereoselective fashion establishing the relative configuration at up to four stereogenic centers.
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(2019)
