115224-13-0Relevant articles and documents
Synthesis and catalytic application of chiral 1,1′-bi-2-naphthol-and biphenanthrol-based pincer complexes: Selective allylation of sulfonimines with allyl stannane and allyl trifluoroborate
Aydin, Juhanes,Kumar, K. Senthil,Sayah, Mahmoud J.,Wallner, Olov A.,Szabo, Kalman J.
, p. 4689 - 4697 (2007)
(Chemical Equation Presented) New easily accessible 1,1′-bi-2- naphthol- (BINOL-) and biphenanthrol-based chiral pincer complex catalysts were prepared for selective (up to 85% enantiomeric excess) allylation of sulfonimines. The chiral pincer complexes w
Enantioselective Strecker and Allylation Reactions with Aldimines Catalyzed by Chiral Oxazaborolidinium Ions
Kang, Ki-Tae,Park, Sang Hyun,Ryu, Do Hyun
, p. 6679 - 6683 (2019/09/12)
Chiral oxazaborolidinium ion (COBI)-catalyzed enantioselective nucleophilic addition reactions of aldimines using tributyltin cyanide and allyltributylstannane have been developed. Various α-aminonitriles and homoallylic amines were synthesized in high yi
Copper-catalyzed asymmetric allylation of chiral N-tert-butanesulfinyl imines: Dual stereocontrol with nearly perfect diastereoselectivity
Zhao, Yi-Shuang,Liu, Qiang,Tian, Ping,Tao, Jing-Chao,Lin, Guo-Qiang
, p. 4174 - 4178 (2015/04/14)
Copper-catalyzed asymmetric allylation of chiral N-tert-butanesulfinyl imines has been described. Dual stereocontrol, through the combination of a chiral auxiliary and a chiral copper complex, has played an important role in achieving the nearly perfect d