231617-04-2

Basic information

• Product Name: (R)-N-acetyl-4-amino-4-phenyl-1-butene
• Synonyms: (R)-N-acetyl-4-amino-4-phenyl-1-butene
• CAS NO: 231617-04-2
• Molecular Weight: 189.257
• Mol File: 231617-04-2.mol

Chemical Properties

• CAS DataBase Reference: (R)-N-acetyl-4-amino-4-phenyl-1-butene(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-N-acetyl-4-amino-4-phenyl-1-butene(231617-04-2)
• EPA Substance Registry System: (R)-N-acetyl-4-amino-4-phenyl-1-butene(231617-04-2)

Safety Data

• Hazardous Substances Data: 231617-04-2(Hazardous Substances Data)

Upstream product

• 108-21-4 Isopropyl acetate 
• 4383-23-7 1-phenyl-but-3-enylamine 
• 141-78-6 ethyl acetate 
• 108-24-7 acetic anhydride 
• 115224-13-0 (R)-4-amino-4-phenyl-1-butene 
• 196929-85-8 (R)-N-benzylidene-2-methylpropane-2-sulfinamide 
• 915089-09-7 (R)-2-methyl-N-((R)-1-phenylbut-3-en-1-yl)propane-2-sulfinamide 
• 231617-03-1 N-[1-(2,5-dimethoxy-phenyl)-ethyl]-N-(1-phenyl-but-3-enyl)-acetamide 

Downstream Products

• 117020-31-2 (R)-N-acetyl-3-amino-3-phenylpropionic acid 
• 115224-13-0 (R)-4-amino-4-phenyl-1-butene 

Relevant articles and documents

Copper-catalyzed asymmetric allylation of chiral N-tert-butanesulfinyl imines: Dual stereocontrol with nearly perfect diastereoselectivity

Copper-catalyzed asymmetric allylation of chiral N-tert-butanesulfinyl imines has been described. Dual stereocontrol, through the combination of a chiral auxiliary and a chiral copper complex, has played an important role in achieving the nearly perfect d

Synthesis of enantiopure benzyl homoallylamines by indium-mediated barbier-type allylation combined with enzymatic kinetic resolution: Towards the chemoenzymatic synthesis of N-containing heterocycles

Barbier-type indium-mediated allylations of different N, N(dimethylsulfamoyl)-protected aldimines with a number of allyl bromides followed by high-yielding deprotection afforded allylic amines in good to excellent yields, The racemic amines were then subj

Design, synthesis, and optical resolution of a novel non-natural chiral auxiliary, 1-(2,5-dimethoxyphenyl)ethylamine. Application to diastereoselective alkylation of aldimines

A chiral amine; 1-(2,5-dimethoxyphenyl)ethylamine, was found to be an effective chiral auxiliary for the diastereoselective alkylation of its aldimines with alkylmetals. The 1-(2,5-dimethoxyphenyl)ethyl group of the chiral auxiliary could be removed by the acetylation and then oxidation of the resultant alkylated product, accompanying an amino-transfer from the chiral auxiliary to the final product. Racemic 1-(2,5- dimethoxyphenyl)ethylamine could be easily synthesized from 1,4- dimethoxybenzene and resolved by the diastereomeric salt formation with mandelic acid to give both enantiomers in pure forms.