115240-91-0

Basic information

• Product Name: 2-(HYDROXY-P-TOLYL-METHYL)-ACRYLIC ACID METHYL ESTER
• Synonyms: 2-(HYDROXY-P-TOLYL-METHYL)-ACRYLIC ACID METHYL ESTER;Methyl 2-(hydroxy(p-tolyl)methyl)acrylate
• CAS NO: 115240-91-0
• Molecular Formula: C₁₂H₁₄O₃
• Molecular Weight: 206.23776
• Mol File: 115240-91-0.mol
• Article Data: 70

Chemical Properties

• Appearance: /
• Storage Temp.: 2-8°C
• CAS DataBase Reference: 2-(HYDROXY-P-TOLYL-METHYL)-ACRYLIC ACID METHYL ESTER(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(HYDROXY-P-TOLYL-METHYL)-ACRYLIC ACID METHYL ESTER(115240-91-0)
• EPA Substance Registry System: 2-(HYDROXY-P-TOLYL-METHYL)-ACRYLIC ACID METHYL ESTER(115240-91-0)

Safety Data

• Hazardous Substances Data: 115240-91-0(Hazardous Substances Data)

Usage

Structure

2-(hydroxy-p-tolyl-methyl)-acrylic acid methyl ester

Type of compound

Methyl ester of the hydroxytoluene derivative of acrylic acid

Uses

Production of adhesives and coatings, formulation of specialty chemicals, raw material for synthesis of pharmaceuticals and agrochemicals

Handling and storage

Standard chemical handling protocols to ensure safety and prevent potential hazards.

Upstream product

• 5445-17-0 Methyl 2-bromopropionate 
• 104-87-0 4-methyl-benzaldehyde 
• 67-56-1 methanol 
• 140-88-5 ethyl acrylate 
• 1187847-13-7 methyl 2-((tert-butoxycarbonyloxy)(4-methylphenyl)methyl)acrylate 
• 292638-85-8 acrylic acid methyl ester 

Downstream Products

• 143165-01-9 methyl 2-(acetoxy(4-methylphenyl)methyl)acrylate 
• 673452-02-3 (E)-2-(acetylamino-methyl)-3-p-tolyl-acrylic acid methyl ester 
• 1163119-70-7 (2R,3S)-(-)-methyl 3-hydroxy-2-methyl-3-(4-methylphenyl)propanoate 
• 885612-67-9 2-aminomethyl-3-(4-methylphenyl)acrylic acid methyl ester 
• 126356-05-6 methyl (E)-2-methyl-3-(4-methylphenyl)acrylate 
• 25860-59-7 -2-methyl-3-(4-methylphenyl)prop-2-enoic acid 
• 107673-39-2 2-(4-Methyl-benzyl)-acrylic acid 

Relevant articles and documents

Ionic liquids as a recyclable reaction medium for the Baylis-Hillman reaction

The Baylis-Hillman reaction using 1,4-diazabicyclo[2.2.2]octane (DABCO) has been shown to be 33.6 times faster in the recyclable ionic liquid 1-n-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF6]) than in acetonitrile. Low yields (14-2

Synthesis and characterization of chiral enantiopure bis-chromanones: a Baylis-Hillman approach

Enantiopure bis-chromanones were prepared from (S)-Binol and bromo esters via a Baylis-Hillman approach. Chiroptical studies indicate that the two-naphthyl units of the chromanone system are non-coplanar.

Microwave-Assisted 1,3-Dioxa-[3,3]-Sigmatropic Rearrangement of Substituted Allylic Carbamates: Application to the Synthesis of Novel 1,3-Oxazine-2,4-dione Derivatives

In a first instance, the effect of the microwave irradiation on the 1,3-Dioxa-[3,3]-sigmatropic rearrangement of aryl allylic carbamates was investigated. Under these new conditions, the reaction acceleration was clearly highlighted compared to convention

Phosphine-Catalyzed [3 + 2] Annulation of Morita-Baylis-Hillman Carbonates with Isoxazole-Based Alkenes

A phosphine-catalyzed [3 + 2] annulation of Morita-Baylis-Hillman (MBH) carbonates with 3-methyl-4-nitro-5-styrylisoxazoles has been developed to afford various multifunctional isoxazoles in moderate to good yields with moderate to excellent diastereoselectivities. With a spirocyclic chiral phosphine as the catalyst, up to 89% ee was obtained.