115259-75-1

Upstream product

• 108-24-7 acetic anhydride 
• 23558-05-6 3-O-benzyl-1,2-O-isopropylidene-1,5-D-xylo-dialdofuranose 
• 34370-91-7 3-O-benzyl-1,2-O-isopropylidene-α-D-xylofuranose 
• 75-36-5 acetyl chloride 
• 18685-18-2 3-O-benzyl-1,2-5,6-O-diisopropylidene-α-D-glucofuranose 
• 100-39-0 benzyl bromide 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 

Downstream Products

• 160140-44-3 Trifluoro-methanesulfonic acid (2R,3S,4R,5R)-3,4-bis-benzyloxy-5-phenylsulfanyl-tetrahydro-furan-2-ylmethyl ester 
• 164217-36-1 (1R,3S,4S,7R,8R,11R,12S,13R)-4,12,13-Tris-benzyloxy-8-(4-methoxy-phenyl)-2,9,14-trioxa-6-aza-tricyclo[9.2.1.0^3,7]tetradecane-6-carboxylic acid benzyl ester 
• 160140-46-5 (2S,3S,4S)-4-Benzyloxy-2-[(R)-((2R,3S,4R,5R)-3,4-bis-benzyloxy-5-phenylsulfanyl-tetrahydro-furan-2-ylmethoxy)-(4-methoxy-phenyl)-methyl]-3-hydroxy-pyrrolidine-1-carboxylic acid benzyl ester 
• 160140-45-4 (2R,3S,4S)-4-Benzyloxy-2-[(R)-((2R,3S,4R,5R)-3,4-bis-benzyloxy-5-phenylsulfanyl-tetrahydro-furan-2-ylmethoxy)-(4-methoxy-phenyl)-methyl]-3-(tetrahydro-pyran-2-yloxy)-pyrrolidine-1-carboxylic acid benzyl ester 
• 160140-48-7 phenyl 3-O-benzyl-5-O-(t-butyldimethylsilyl)-1-thio-α-D-xylofuranoside 
• 160140-49-8 phenyl 3-O-benzyl-5-O-(t-butyldimethylsilyl)-1-thio-β-D-xylofuranoside 
• 164217-39-4 phenyl 2,3-di-O-benzyl-1-thio-β-D-xylofuranoside 
• 160140-43-2 phenyl 2,3-di-O-benzyl-1-thio-α-D-xylofuranoside 

Relevant academic research and scientific papers

Total synthesis of cephalosporolide E via a tandem radical/polar crossover reaction. The use of the radical cations under nonoxidative conditions in total synthesis

The present work reports the first example of the use of the chemistry of radical cations under nonoxidative conditions in total synthesis. Using a late-stage tandem radical/polar crossover reaction, a highly stereoselective total synthesis of cephalospor

The reaction of (methylthio)acetyliron complex with pentose terminal aldehydes

The reaction between anion generated from (methylthio)acetyliron complex (1) and four stereoisomeric dialdo-1,4-furanoses was performed. Each aldehyde led to mixtures (6-8) of stereoisomeric aldols. Aldols were separated and their configuration was determ