Welcome to LookChem.com Sign In|Join Free

CAS

  • or

1155-00-6

Post Buying Request

1155-00-6 Suppliers

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier

1155-00-6 Usage

Chemical Properties

yellow to yellow-green crystalline powder

Uses

Bis(o-Nitrophenyl) Disulfide, can be used in a PVC membrane electrode as a sensor for zinc ions. It is also a building block used for the synthesis of various pharmaceutical compounds. It can be used for the preparation of a series of 4-Azaindole inhibitors of c-Met kinase.

General Description

PVC membrane electrode based on bis(2-nitrophenyl)disulfide carrier acts as sensor for zinc ions. Bis(2-nitrophenyl) disulphide undergoes mechanochemical grinding with bis(4-chlorophenyl)disulfide in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene catalyst via metathesis reaction to yield non-symmetrical heterodimer 4-chlorophenyl-2′-nitrophenyl disulfide.

Purification Methods

Purify the disulfide by recrystallisation from glacial AcOH or from *C6H6 and the yellow needles are dried in an oven at 100o until the odour of the solvent is absent. It is sparingly soluble in EtOH and Me2CO. [Bogert & Stull Org Synth Coll Vol I 220 1941, Bauer & Cymerman J Chem Soc 3434 1949, Beilstein 6 IV 1672.]

Check Digit Verification of cas no

The CAS Registry Mumber 1155-00-6 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,1,5 and 5 respectively; the second part has 2 digits, 0 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 1155-00:
(6*1)+(5*1)+(4*5)+(3*5)+(2*0)+(1*0)=46
46 % 10 = 6
So 1155-00-6 is a valid CAS Registry Number.
InChI:InChI=1/C12H8N2O4S2/c15-13(16)9-5-1-3-7-11(9)19-20-12-8-4-2-6-10(12)14(17)18/h1-8H

1155-00-6 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • Aldrich

  • (215228)  Bis(2-nitrophenyl)disulfide  99%

  • 1155-00-6

  • 215228-25G

  • 539.37CNY

  • Detail

1155-00-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name Bis(2-nitrophenyl) disulfide

1.2 Other means of identification

Product number -
Other names Bis(2-nitrophenyl) Disulfide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1155-00-6 SDS

1155-00-6Relevant articles and documents

Bromonitromethane, a Versatile Electrophile: Reactions with Thiolates

Fishwick, Brian R.,Rowles, David K.,Stirling, Charles J. M.

, p. 834 - 835 (1983)

Thiolate ions react with bromonitromethane to give nitronate ion and, initially, sulphenyl bromide which reacts with further thiolate ion to give disulphide; when the disulphide bears an appropriately placed nitrile function, intramolecular attack by the nitronate ion at this function and subsequent intramolecular displacement of thiolate ion yields aminothiophenes.

Synthesis and structural study of 1-(N,N-diethylamino)-2,2-bis(2-nitrophenylthio)ethene

Aupers, John H.,Skakle, Janet M.S.,Wardell, James L.,Wardell, Solange M.S.V.

, p. 435 - 443 (2001)

The synthesis, variable temperature NMR spectra, and crystal structures of two crystalline forms, 2a and 2b, of the enamine 1-(N,N-diethylamino)-2,2-bis(2-nitrophenylthio)ethene have been obtained. Both forms crystallize in the monoclinic space group P21/a. The two phases have similar molecular structures but possess different intermolecular C - H ... O hydrogen bonding interactions. Both forms exhibit disorder within the NEt2 fragment at 298 K: sufficient disorder persisted with 2a (orange needles) down to 100 K to make the geometric parameters pertaining to the enamine fragment unreliable. The disorder was effectively eliminated on cooling 2b down (red colored blocks) to 150 K. Cell dimensions for the 2a-phase are at 100 K: a = 11.1030(4) A, b = 15.1325(7) A, c = 12.4504(7) A, β = 114.606(3)°, while for the 2b-phase at 150 K, a = 15.5206(4) A, b = 7.6958(2) A, c = 15.7137(3) A, β = 92.580(7)°. The C - N bond length in the β-form at 150 K of 1.335(3) A indicates considerable double bond character: the rotational barrier of the C - N bond in CDCl3 was calculated to be 52.4 kJ mol-1.

-

Milligan,Swan

, p. 2172,2174 (1962)

-

-

Zeifman,Yu.V. et al.

, (1978)

-

Palladium-Catalyzed Picolinamide-Directed Benzylic C(sp3)?H Chalcogenation with Diaryl Disulfides and Diphenyl Diselenide

Wang, Kai,Hou, Jiahao,Zhang, Changjun,Cheng, Ke,Bai, Renren,Xie, Yuanyuan

supporting information, p. 2947 - 2952 (2020/06/17)

The first palladium-catalyzed direct benzylic C(sp3)?H chalcogenation with diaryl disulfides and diphenyl diselenide has been established. The coupling reaction proceeds between the thioether radical and palladiumcycle intermediate. Picolinamide serves as an excellent directing group for the C?H activation of benzylic C(sp3)?H and can be easily removed. The current protocol exhibits a relatively broad substrate scope and high functional group compatibility. A mechanistic study indicates that palladium(IV) intermediate is probably formed during the course of the reaction. (Figure presented.).

Synthesis and nano-Pd catalyzed chemoselective oxidation of symmetrical and unsymmetrical sulfides

Li, Xing,Du, Jia,Zhang, Yongli,Chang, Honghong,Gao, Wenchao,Wei, Wenlong

, p. 3048 - 3055 (2019/03/21)

A highly chemoselective, efficient and nano-Pd catalyzed protocol for the rapid construction of sulfoxides and sulfones via the oxidation of symmetrical and unsymmetrical sulfides using H2O2 as an oxidant has been developed, respectively. The ready availability of starting materials, easy recovery and reutilization of the catalyst, wide substrate scope, and high yields make this protocol an attractive alternative. The process also involves the metal-free and microwave-promoted synthesis of symmetrical diarylsulfides, and FeCl3-mediated preparation of symmetrical diaryldisulfides through the reaction of arenediazonium tetrafluoroborates with Na2S·9H2O as a sulfur source. In addition, unsymmetrical sulfides were generated via the K2CO3-mediated reaction of arenediazonium tetrafluoroborates with symmetrical disulfides.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 1155-00-6