2253-67-0

Basic information

• Product Name: BIS(2,4-DINITROPHENYL) DISULFIDE
• Synonyms: sulfide,bis(2,4-dinitrophenyl);2,2',4,4'-TETRANITRODIPHENYL DISULFIDE;BIS(2,4-DINITROPHENYL) DISULFIDE;2,4-DINITROPHENYL SULFIDE
• CAS NO: 2253-67-0
• Molecular Formula: C₁₂H₆N₄O₈S
• Molecular Weight: 398.33
• Mol File: 2253-67-0.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 530.2°Cat760mmHg
• Flash Point: 274.5°C
• Appearance: /
• Density: 1.74g/cm³
• CAS DataBase Reference: BIS(2,4-DINITROPHENYL) DISULFIDE(CAS DataBase Reference)
• NIST Chemistry Reference: BIS(2,4-DINITROPHENYL) DISULFIDE(2253-67-0)
• EPA Substance Registry System: BIS(2,4-DINITROPHENYL) DISULFIDE(2253-67-0)

Safety Data

• Hazardous Substances Data: 2253-67-0(Hazardous Substances Data)

Upstream product

• 64-17-5 ethanol 
• 127-09-3 sodium acetate 
• 79-19-6 thiosemicarbazide 
• 97-00-7 1-chloro-2,4-dinitro-benzene 
• 17356-08-0 thiourea 
• 333-20-0 potassium thioacyanate 
• 140-89-6 potassium ethyl xanthogenate 
• 584-48-5 2,4-dinitrobromobenzene 
• 540-72-7 sodium thiocyanide 
• 709-49-9 1-iodo-2,4-dinitrobenzene 
• 70-34-8 2,4-Dinitrofluorobenzene 
• 126990-08-7 2,2-Dimethyl-4,6-dioxo-[1,3]dioxane-5-carbothioic acid p-tolylamide 
• 88-73-3 2-Chloronitrobenzene 
• 610-31-1 1,2,4-trinitrobenzene 

Downstream Products

• 51256-42-9 Sodium 2,4-dinitrophenyl sulfide 
• 108-45-2 m-phenylenediamine 
• 7343-55-7 2,4-dinitrophenyl ethyl sulfide 
• 2486-12-6 bis-(2,4-dinitro-phenyl) sulfone 
• 52427-27-7 2,2',4,4'-tetranitrodiphenylsulfoxide 
• 2217-55-2 bis(2,4-dinitrophenyl) disulphide 
• 52386-09-1 5-amino-3H-benzothiazole-2-thione 

Relevant articles and documents

Magnetically recoverable ferromagnetic 3D hierarchical core-shell Fe3O4@NiO/Co3O4 microspheres as an efficient and ligand-free catalyst for C–S bond formation in poly (ethylene glycol)

A simple and efficient protocol for the synthesis of diaryl thioethers from the reaction of thiourea with a wide variety of aryl halides, including aryl iodides, aryl bromides and aryl chlorides in the presence of 3D hierarchical core-shell Fe3O4@NiO/Co3O4 microspheres has been described. This reaction enables the one-pot synthesis of diaryl thioethers in good to high yields using a non-toxic and magnetically separable catalyst in PEG-400 as an eco-friendly, safe, inexpensive and thermally stable solvent. Magnetic separation and reusability of catalyst for eight times without any significant loss of activity, the use of a commercially available, eco-friendly, cheap and chemically stable sulfur transfer agent and solvent, operational simplicity, environmentally benign, easier work-up procedure and cost efficiency make this method a promising candidate for potential applications in some organic reactions. The catalytic activity of Fe3O4@NiO/Co3O4 as a novel and inexpensive catalyst was investigated in the C-S cross coupling reaction.

Reactions of Meldrum's Acid with Isocyanates and Isothiocyanates

Meldrum's acid (1) reacts with isothiocyanates and LiH as base, yielding after alkylation the ketene-S,N-acetales 3, 4 and 5.Protonation of the lithium-thiolate 2 gives the thioamides 7 with tautomers 8, which can be methylated with diazomethane to 9.From

ACTION OF ALKALI METALS IN LIQUID AMMONIA ON SUBSTITUTED THIOPHENES. COMMUNICATION 9. PREPARATION OF 5-MERCAPTO-4-KETOALKANOIC ACIDS BY REDUCTIVE CLEAVAGE OF 4-ACETYLAMINO- AND 4-NITROTHIOPHENE-2-CARBOXYLIC ACIDS

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