115802-63-6Relevant academic research and scientific papers
A Next-Generation Air-Stable Palladium(I) Dimer Enables Olefin Migration and Selective C?C Coupling in Air
Kundu, Gourab,Rissanen, Kari,Schoenebeck, Franziska,Sperger, Theresa
supporting information, p. 21930 - 21934 (2020/10/02)
We report a new air-stable PdI dimer, [Pd(μ-I)(PCy2tBu)]2, which triggers E-selective olefin migration to enamides and styrene derivatives in the presence of multiple functional groups and with complete tolerance of air. The same dimer also triggers extremely rapid C?C coupling (alkylation and arylation) at room temperature in a modular and triply selective fashion of aromatic C?Br, C?OTf/OFs, and C?Cl bonds in poly(pseudo)halogenated arenes, displaying superior activity over previous PdI dimer generations for substrates that bear substituents ortho to C?OTf.
Nickel(0)-Catalyzed N-Allylation of Amides and p-Toluenesulfonamide with Allylic Alcohols under Neat and Neutral Conditions
Azizi, Mohamed Salah,Edder, Youssef,Karim, Abdallah,Sauthier, Mathieu
, p. 3796 - 3803 (2016/08/16)
Nickel(0)-catalyzed direct N-allylation of amides and p-toluenesulfonamide with allylic alcohols took place in the presence of Ni0–diphosphine complexes. The corresponding N-allylated (and/or N,N-diallylated) products were obtained in moderate to high yields under neutral conditions.
Visible-light-induced photocatalytic reductive transformations of organohalides
Kim, Hyejin,Lee, Chulbom
supporting information, p. 12303 - 12306 (2013/02/23)
A photo opportunity: A visible-light-excited iridium catalyst delivers electrons from an amine to an organohalide. The electron transfer then induces reductive scission of the carbon-halogen bond, generating the corresponding alkyl, alkenyl, and aryl radical that can undergo cyclization and hydrodehalogenation reactions. Copyright
Highly selective synthesis of (E)-N-aryl-N-(1-propenyl) ethanamides via isomerization of N-allyl ethanamides catalyzed by ruthenium complexes
Krompiec, Stanislaw,Pigulla, Mariola,Szczepankiewicz, Wojciech,Bieg, Tadeusz,Kuznik, Nikodem,Leszczynska-Sejda, Katarzyna,Kubicki, Maciej,Borowiak, Teresa
, p. 7095 - 7098 (2007/10/03)
A convenient and highly selective method of synthesis of (E)-N-aryl-N-(1-propenyl)ethanamides via isomerization of respective N-allyl-N-arylethanamides catalyzed by [RuClH(CO)(PPh3)3] has been described. N-Allyl-N-arylethanamides hav
THE REACTIONS OF ALLYL o-BROMOARYL ETHERS, N-ALLYL o-BROMOACETANILIDE, AND RELATED COMPOUNDS WITH TRIBUTYLTIN HYDRIDE IN THE PRESENCE OF ACTIVATED OLEFINS
Togo, Hideo,Kikuchi, Osamu
, p. 373 - 381 (2007/10/02)
o-Bromophenyl allyl ether, N-allyl o-bromoacetanilide, and related compounds reacted with tributyltin hydride in the presence of activated olefins to give 2,3-dihydrobenzofuran, 2,3-dihydroindole, and analogous derivatives in modest yields respectively vi
INTRAMOLECULAR RADICAL CYCLIZATION REACTIONS. AN APPROACH TO THE INDOLE ALKALOIDS
Dittami, James P.,Ramanatham, Halasya
, p. 45 - 48 (2007/10/02)
The intramolecular radical cyclization reaction of N-allyl substituted derivates of o-bromoacetanilide provides a short and effective route to a variety of dihydroindole systems.
