116008-49-2Relevant academic research and scientific papers
Liquid-phase and biphasic chlorination of some iodoarenes to form (dichloroiodo)arenes with sodium peroxodisulfate as the oxidant
Baranowski,Plachta,Skulski,Klimaszewska
, p. 435 - 437 (2007/10/03)
Liquid-phase and biphasic (CCl4/concd hydrochloric acid) chlorination of some iodoarenes to form the corresponding (dichloroiodo)arenes, prepared in 60-100% crude yields, are reported; dichlorine is produced as follows: Na2S2OP8 + 2 HCl (conc. aq.) → Cl2 + 2 NaHSO4.
Biphasic chlorination of iodoarenes to (dichloroiodo)arenes
Krassowska-?wiebocka, Barbara,Prokopienko, Grazyna,Skulski, Lech
, p. 1409 - 1410 (2007/10/03)
A two-phase (CCl4/conc. hydrochloric acid) chlorination of some iodoarenes to the corresponding (dichloroiodo)arenes, prepared in 50-98% crude yields, is reported. Dichlorine is produced in the aqueous phase as follows: KClO3 (solid) + 6 HCl (conc. aq.) → ↑3Cl2 + KCl + 3H2O.
