116724-11-9

Basic information

• Product Name: (S)-Butyl-⁽²⁾-isothiocyanat
• CAS NO: 116724-11-9
• Molecular Weight: 115.199
• Mol File: 116724-11-9.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: (S)-Butyl-⁽²⁾-isothiocyanat(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-Butyl-⁽²⁾-isothiocyanat(116724-11-9)
• EPA Substance Registry System: (S)-Butyl-⁽²⁾-isothiocyanat(116724-11-9)

Safety Data

• Hazardous Substances Data: 116724-11-9(Hazardous Substances Data)

Upstream product

• 33966-50-6 SEC-BUTYLAMINE 
• 96989-50-3 di-2-pyridyl thionocarbonate 
• 14069-89-7 (+/-)sec-butyl isocyanide 
• 75-15-0 carbon disulfide 
• 463-71-8 thiophosgene 
• 31519-50-3 (S)-1-methylpropylamine hydrochloride 
• 88064-52-2 1-(s-butyl)-2,4,6-triphenylpyridinium tiocyanate 

Downstream Products

• 51098-18-1 sec-Butyl-dithiocarbamic acid p-tolyl ester 
• 767329-46-4 tert-butyl 2-{5-{[(sec-butylamino)carbonothioyl]amino}-2-[(3,4,5-trimethoxyphenyl)amino]-3H-imidazo[4,5-b]pyridin-3-yl}ethylcarbamate 
• 14117-23-8 (S)-N-(sec-butyl)-N'-benzyl-urea 
• 852675-21-9 R/S-N-(2-amino-5-methylsulfonylbenzenesulfonyl)-N'-2-butylthiourea 
• 31182-22-6 N_.N'-di-(sec-butyl)-thiourea 
• 6814-99-9 (S)-1--thioharnstoff 
• 16885-29-3 N-((S)-sec-butyl)-N'-phenyl-thiourea 
• 6814-99-9 N-(sec-butyl)thiourea 
• 4312-11-2 4-sec-butyl-thiosemicarbazide 
• 513-49-5 (S)-2-aminobutane 
• 33966-50-6 SEC-BUTYLAMINE 
• 802328-69-4 1-sec-Butyl-3-{4-[N'-(4-chloro-phenyl)-guanidino]-phenyl}-thiourea 
• 32497-67-9 4-(N'-sec-Butyl-guanidino)-N-(4-chloro-phenyl)-benzamidine 

Relevant articles and documents

Direct, Microwave-Assisted Synthesis of Isothiocyanates

A microwave-assisted desulfuration of readily available dithiocarbamates, formed in situ from primary amines, leading to target isothiocyanates has been developed. This efficient protocol provides a rapid, environmentally benign route to aliphatic and aromatic isothiocyanates.

Novel selenium catalyzed synthesis of isothiocyanates from isocyanides and elemental sulfur

A variety of aliphatic and aromatic isothiocyanates were synthesized in good to excellent yields from corresponding isocyanides and elemental sulfur under mild conditions by use of catalytic amounts of elemental selenium.

Phosphine-Substituted Chelate Ligands, XXV. Diastereoselective Complexation of Chiral Phosphinothioformamides with Remote Asymmetric Centre

For further studies of the diastereoselective complex formation of ambidentate chiral chelating ligands, we prepared the racemic phosphinothioformamides, Ph2P(X)C(S)NHC*HR1R2, with X = 2e- (R1 = Ph, R2 = Et: 1a; R1 = Ph, R2 = iPr: 2a; R1 = Me, R2 = Et: 3a) and X = O (1b, 2b) according to a previously reported route.The coordination of 1a-3a to CpM(CO)3Cl (M = Mo, W) in methanol gives the diastereomeric P,S-chelate complexes, (Mo: 4-6, W :7-9).In solution, epimerisation proceeds to an equilibrium ratio of B/A = 1.5 in case of 4, 5, 7, and 8, but less than 1.1 with 6 and 9.A reduced diastereoselectivity (d.e. 10-20percent) is also observed during the formation of the analogous molybdenum complexes 10a-d with phosphine ligands derived from α-amino acid esters, Ph2PC(S)NHC*H(R)COOMe .The results indicate a significant asymmetric induction despite of the four bond distance of the chiral centres. - Diastereoselectivity, Chiral Phosphinothioformamides, Amino Acid Esters, Remote Asymmetric Centre, Cyclopentadienyl Molybdenum and Tungsten Complexes