116831-06-2

Basic information

• Product Name: (S)-ethyl cyclohexanone-2-(2-carboethoxy-ethyl)-2-carboxylate
• Synonyms: (S)-ethyl cyclohexanone-2-(2-carboethoxy-ethyl)-2-carboxylate
• CAS NO: 116831-06-2
• Molecular Weight: 270.326
• Mol File: 116831-06-2.mol

Chemical Properties

• CAS DataBase Reference: (S)-ethyl cyclohexanone-2-(2-carboethoxy-ethyl)-2-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-ethyl cyclohexanone-2-(2-carboethoxy-ethyl)-2-carboxylate(116831-06-2)
• EPA Substance Registry System: (S)-ethyl cyclohexanone-2-(2-carboethoxy-ethyl)-2-carboxylate(116831-06-2)

Safety Data

• Hazardous Substances Data: 116831-06-2(Hazardous Substances Data)

Upstream product

• 53898-03-6 2-(S-1-phenylethylamino)-cyclohex-1-enecarboxylic acid ethyl ester 
• 140-88-5 ethyl acrylate 
• 1655-07-8 ethyl 2-oxocyclohexane carboxylate 
• 121506-74-9 ethyl (-)-N-<(R)-1-phenylethyl>-1-aminocyclohexene-2-carboxylate 
• 104316-13-4 2-(1-tert-butoxycarbonyl-2-methyl-propylamino)-cyclohex-1-enecarboxylic acid ethyl ester 

Relevant articles and documents

Stereoselective Reactions. XXIV. Chlorotrimethylsilane Promoted Asymmetric Michael Reaction of Chiral Lithioenamines Derived from α-Alkyl β-Keto Esters

Chlorotrimethylsilane promoted asymmetric Michael reaction of the chiral lithioenamines derived from α-alkyl β-keto esters and (S)-valine tert-butyl ester is described.Complementary asymmetric syntheses producing either enantiomers from the same starting

CHLOROTRIMETHYLSILANE PROMOTED ASYMMETRIC MICHAEL REACTION OF CHIRAL ENAMINES OF α-ALKYL β-KETO ESTERS

By the promotion of chlorotrimethylsilane, asymmetric Michael reaction of the chiral enamines (2) of α-alkyl β-keto esters (1) with methyl vinyl ketone and ethyl acrylate proceeded to afford, after hydrolysis, either enantiomer of the corresponding adduct

SUBSTITUTED SPIRO AZABICYCLICS AS MODULATORS OF CHEMOKINE RECEPTOR ACTIVITY

The present application describes modulators of CCR3 of formula (Ia) and (Ib): (I) or pharmaceutically acceptable salt forms thereof, wherein Z, R1, R2, R3, R4, R5, R5', R6, a, b

Catalytic asymmetric Michael reaction promoted by the La-Na-BINOL complex (LSB). Enantioface selection on Michael donors

LSB can efficiently promote catalytic asymmetric Michael reactions in CH2Cl2, inducing high enantiomeric excesses on the Michael donor side. The multifunctional character of LSB appears to give rise to high stereoselectivity, offerin

Synthesis of optically active α,α-distubstituted β-keto esters via chiral β-enamino esters

Michael addition of chiral β-enamino esters to MVK and acrylates promoted by Lewis acids (ZnCl2, MgBr2) or high pressure (11-14 Kbar) afforded, after hydrolytic work-up, α,α-disubstituted β-keto esters in good enantiomeric carbon exc

Synthesis of Optically Active Michael Adducts Via Chiral Enamines

Chiral enamines, obtained by Schiff base condensation from 1,3-dicarbonyl compounds and (R)-(+)-1-phenylethylamine, were found to undergo diastereoselective Michael reactions with α,β-unsaturated carbonyl compounds.After removal of the chiral auxiliary (R